5-硝基糠醛缩胺类化合物的合成  

Synthesis of 5-nitro-furfuralimine compounds

作　　者：刘浪[1] 李鸿波[1] 马昌鹏[1] 陈凯[1] 

机构地区：[1]西南科技大学材料科学与工程学院,四川绵阳621010

出　　处：《云南大学学报（自然科学版）》2012年第3期329-332,347,共5页Journal of Yunnan University(Natural Sciences Edition)

基　　金：西南科技大学研究生创新基金资助项目(11ycjj10)

摘　　要：以糠醇为原料,经酯化,硝化,水解,氧化制得关键中间体5-硝基糠醛,总收率51%;再与胺类化合物反应合成了一系列5-硝基糠醛缩胺类化合物,收率71%～89%.产物及中间体经IR,1H NMR,MS确证结构.The key intermediate of 5 - nitro - furfuraldehyde was synthesized from furfuryl alcohol by esterifi- cation, nitration, hydration and oxidation, the total yield was 51%. A series of 5 - nitro - furfuralimine compounds were prepared form 5 - nitro - furfuraldehyde with various amines in the yield of 71% --89 %. The structures of the products and intermediate were confirmed by IR, 1H NMR and MS.

关 键 词：5-硝基糠醛 5-硝基糠醛缩胺类化合物 有机合成 

分 类 号：O626.11[理学—有机化学]