Controllable self-assemblies of β-cyclodextrin-calix[4]arene couples  

作　　者：LI Liang ZHANG HengYi LIU Yu 

机构地区：[1]State Key Laboratory of Elemento-Organic Chemistry,Department of Chemistry, Nankai University, Tianjin 300071, China

出　　处：《Science China Chemistry》2012年第6期1092-1096,共5页中国科学(化学英文版)

基　　金：supported by the National Basic Research Program of China (973 Program, 2011CB932500);National Natural Science Foundation of China (20932004)

摘　　要：Arnphiphilic cyclodextrin-calixarene conjugates 1 and 2 were synthesized from "click claemxstry, and tnelr sen-asscmuly uchaviors were investigated by transmission electron microscopy, and atomic force microscopy. The results obtained show that 1 and 2 can self-assemble to form distinctly different aggregations, and the morphology of aggregations critically relies on the polarity and hydrophilicity of the solvent.Amphiphilic cyclodextrin-calixarene conjugates 1 and 2 were synthesized from "click chemistry", and their self-assembly behaviors were investigated by transmission electron microscopy, and atomic force microscopy. The results obtained show that 1 and 2 can self-assemble to form distinctly different aggregations, and the morphology of aggregations critically relies on the polarity and hydrophilicity of the solvent.

关 键 词：CYCLODEXTRIN CALIXARENE self-assembly 

分 类 号：O621.2[理学—有机化学]