C-H bond amination by iron-imido/nitrene species  

作　　者：ZHANG Long DENG Liang 

机构地区：[1]State Key Laboratory of Organometallic Chemistry,Shanghai Institute∥Organic Chemistry,Chinese Academy of Sciences,Shanghai 200032,China

出　　处：《Chinese Science Bulletin》2012年第19期2352-2360,共9页

基　　金：supported by the National Basic Research Program of China(2011CB808705);the National Natural Science Foundation of China(21002114 and 20872168)

摘　　要：C-H amination by iron-imido/nitrene species has attracted increasing research interest in recent years because of its potential use in economical and environmentally benign syntheses of amino compounds.With the aim of providing a comprehensive overview of this field,which is of interest to both the synthetic organic and inorganic communities,this paper reviews the status quo of C-H amination chemistry by iron-imido/nitrene intermediates,as well as by well-defined iron-imido/nitrene compounds,with special emphasis on their structure/reactivity correlations.Achievements,problems,and perspectives in this growing field are discussed.C-H amination by iron-imido/nitrene species has attracted increasing research interest in recent years because of its potential use in economical and environmentally benign syntheses of amino compounds. With the aim of providing a comprehensive overview of this field, which is of interest to both the synthetic organic and inorganic communities, this paper reviews the status quo of C H amination chemistry by iron-imido/nitrene intermediates, as well as by well-defined iron-imido/nitrene compounds, with special emphasis on their structure/reactivity correlations. Achievements, problems, and perspectives in this growing field are discussed.

关 键 词：氨化 C-H键 物种 氨基化合物 潜在用途 中间体 合成 

分 类 号：O621.2[理学—有机化学]