[Cu(L-His)(Phen)]·2ClO_4·H_2O的合成、表征及晶体结构  

Synthesis, Characterization and Crystal Structure of [Cu(L-His) (Phen)]·2ClO_4·H_2O

作　　者：周晓华[1] 乐学义[1] 李明华[1] 

机构地区：[1]华南农业大学理学院应用化学系,广州510642

出　　处：《高等学校化学学报》2000年第5期681-682,共2页Chemical Journal of Chinese Universities

摘　　要：The crystal of [Cu(L-His) (Phen)]·2ClO4·H2O was synthesized and characterized by element analysis, molar conductivity, UV, IR and X-ray single crystal structure. The crystal belongs to monoclinic system, space group P21, with a=1. 222 7(2) nm, b=0. 714 5(14) nm, c=1. 452 0(3) nm, β=109. 82 (3)° V=1. 193 3(4) nm3, Z=2, F(000)=624, Dc=1.711 g/cm3, μ(Mo Ka) =12. 08 cm-1, R=0.050 9, wR=0. 139 2.The crystal of [Cu(L-His) (Phen)]·2ClO4·H2O was synthesized and characterized by element analysis, molar conductivity, UV, IR and X-ray single crystal structure. The crystal belongs to monoclinic system, space group P21, with a=1. 222 7(2) nm, b=0. 714 5(14) nm, c=1. 452 0(3) nm, β=109. 82 (3)° V=1. 193 3(4) nm3, Z=2, F(000)=624, Dc=1.711 g/cm3, μ(Mo Ka) =12. 08 cm-1, R=0.050 9, wR=0. 139 2.

关 键 词：L-组氨酸 邻菲咯啉 晶体结构 铜配合物 

分 类 号：O614.121[理学—无机化学] O627.12[理学—化学]