B_4C/Al中子吸收板腐蚀过程中的起泡研究  

Study on the Blistering of B_4C/Al Neutron Absorber Plate in the Course of Corrosion

作　　者：李刚[1] 王美玲[1] 王贯春[1] 简敏[1] 

机构地区：[1]中国核动力研究设计院反应堆燃料及材料重点实验室,成都600041

出　　处：《表面技术》2012年第4期35-38,共4页Surface Technology

基　　金：中国核动力研究设计院开发基金(M1030)

摘　　要：根据亨利定律,建立了B4C/Al中子吸收板包壳腐蚀起泡的模型,计算了孔隙半径、温度对起泡的影响,并利用孔隙毛细管效应分析了孔隙对中子吸收板起泡的影响。结果表明:孔隙半径越小,腐蚀产生的氢气压力越大,B4C/Al中子吸收板包壳更易起泡;温度对腐蚀产生的氢气压力影响非常小,而孔隙半径是影响氢气压力的主要因素;氢气持续产生并在孔隙毛细管中积聚,是包壳产生起泡的动力;水分容易通过孔隙毛细管在B4C/Al芯体中扩散,可导致Al腐蚀,引起包壳起泡。The corrosion model of cladding blistering on B4C/Al neutron absorber plate was established by Henry＇s law, and by means of the model to investigate the relationship between pore radius and temperature factors for blistering. Influence of pore size for the neutron absorber plate blistering was analyzed by using the pore capillary effects. The results show that the hydrogen pressure produced in small radius pores is higher due to A1 corrosion, which contributed to B4C/A1 neutron absorber plate cladding blistering. Influence of temperature on the corrosion generated hydrogen pressure is very small, but the main factors affecting the hydrogen pressure is the pore radius sizes. Blistering power of the cladding is hydrogen continuous generation and accumulating in the pore capillary. The water diffuses easily through the pore capillary in B4C/Al cores, which will cause the cladding blistering because of Al corrosion.

关 键 词：B4C/Al板 腐蚀 起泡 毛细管效应 

分 类 号：TG172.9[金属学及工艺—金属表面处理]