Hydrophosphonylation of Aldimines under Catalysts-Free Conditions  

作　　者：蔡志华 范业成 杜广芬 何林 

机构地区：[1]Key Laboratory for Green Processing of Chemical Engineering of Xinjiang Bingtuan,School of Chemistry and Chemical Engineering,Shihezi University,Xinjiang 832000,China

出　　处：《Chinese Journal of Chemistry》2012年第7期1658-1662,共5页中国化学（英文版）

摘　　要：Trimethylsilyl phosphite reacted with aldimines efficiently under catalysts-free conditions, giving a-aminophosphonates in good to excellent yields. Furthermore, the reaction can be scaled-up easily and the high yield can be maintained.Trimethylsilyl phosphite reacted with aldimines efficiently under catalysts-free conditions, giving a-aminophosphonates in good to excellent yields. Furthermore, the reaction can be scaled-up easily and the high yield can be maintained.

关 键 词：trimethylsilyl phosphite ALDIMINES a-aminophosphonates catalysts-flee 

分 类 号：O623.731[理学—有机化学] TQ325.14[理学—化学]