supported by the National Natural Science Foundation of China(Nos.21402116 and 21502111);the Key Scientific and Technological Project of Henan Province(No.222102310607);the Key Science Research of Education Committee in Henan Province(Nos.21A150044 and 22A150051);the Shandong Provincial Natural Science Foundation(Nos.ZR2023QH502 and ZR2023QB172);the Doctoral Research Foundation of Zaozhuang University.
We first describe a photoinduced decatungstate-catalyzed direct coupling of cycloalkanes and cyclic aldimines.The desired products were generated in moderate to good yields with wide substrate scope under mild reactio...
supported by the National Key R&D Program of China(2022YFA1506100);National Natural Science Foundation of China(Grant Nos.22371294,and 21821002);the Strategic Priority Research Program of the Chinese Academy of Sciences(Grant No.XDB0610000);Beijing National Laboratory for Molecular Sciences(BNLMS202304).
Catalytic methylative coupling of internal alkynes and aldehydes/aldimines through regioselective oxidative cyclization promoted by a phosphine–Co complex is presented.Such process constitutes an unprecedented and un...
Financial support from the National Natural Science Foundation of China(21772046,2193103 and 22001038);Fuzhou University(510578)is gratefully acknowledged.
Herein we present a diastereoselective addition of arylboronic acids toα-keto N-tert-butanesulfinyl aldi-mines catalyzed by a Rh(I)catalyst.This reaction provides a practical method to obtain valuable chiralα-amino ...
the National Natural Science Foundation of China (21702222, 21821002, 92056103);Shanghai Rising-Star Program (19QA1411000)。
Catalytic generation of cobalt enolates through ring-opening of easily accessible cyclopropanols, subsequent β-hydride elimination and site-selective reinsertion followed by diastereo-and enantioselective additions t...
financially supported by the National Natural Science Foundation of China(Nos.21402116,21502111,21572126);the Science and Technology Innovation Talents of Henan Province(No.2018JQ0011);the Key Science Research of Education Committee in Henan Province(No.21A150044)。
Silver-catalyzed decarboxylative C–H alkylation of cyclic aldimines with abundant aliphatic carboxylic acids has been realized under mild reaction conditions generating the corresponding products in moderate to good ...
Reaction of imines with 2-silyloxydiene catalyzed by ammonium chloride has been perfectly proceeded under environmentally friendly conditions to give Mannich-type product selectively. The reaction would proceed via Ma...
supported by the National Natural Science Foundation of China(21332007);Xiamen University
The direct partial reduction of highly stable secondary amides to more reactive aldimines and aldehydes is a challenging yet highly demanding transformation. In this context, only three methods have been reported. We ...
Mannich-type reactions of aldimines with silyl enolates and hetero Diels-Alder reactions of aldehydes with Danishef-sky’s diene in the presence of anion catalysts derived from proline were performed to afford the cor...
Trimethylsilyl phosphite reacted with aldimines efficiently under catalysts-free conditions, giving a-aminophosphonates in good to excellent yields. Furthermore, the reaction can be scaled-up easily and the high yield...
A series of structurally related diphenol aldimines (DPAs) were synthesized. These aldimines involve different substitution patterns of their phenolic groups, for the purpose of optimizing their ability to inhibit ATP...