supported in part by the National Key Research and Development Program of China(2022YFC2303100);the National Natural Science Foundation of China(32030002,22193070);the Shanghai Post-Doctoral Excellence Program(2022718)。
Cobalamin(Cbl)-dependent radical S-adenosyl-L-methionine(SAM)proteins constitute the largest collection of the radical SAM superfamily that has hundreds of thousands of individual members.Many of these proteins are in...
supported by grants from the Fundamental Research Funds for Central Universities(No.2042021kf0190)。
2-Deoxy-α-C-Glycosides are a significant class of carbohydrates found in numerous bioactive molecules and medicines.Developing a concise strategy for the assembly of theseα-configured C-glycosides is crucial in the ...
financial support provided by the National Natural Science Foundation of China(No.22061032);Natural Science Foundation of Inner Mongolia(Nos.2020MS02022,and 2022QN02005);Science and Technology Program of Inner Mongolia(No.2020GG0134);Opening-fund from State Key Laboratory of Bio-organic and Natural Products Chemistry of SIOC(No.21300-5206002);“JUN-MA”Highlevel Talents Program of Inner Mongolia University(No.21300-5185121);“Grassland Talents”Program of Inner Mongolia(No.12000-12102414);High-level Recruit Program of Inner Mongolia(No.12000-13000603);Key Project at Central Government Level:the ability establishment of sustainable use for valuable Chinese medicine resources(No.2060302)is sincerely acknowledged。
The construction of chiral quaternary carbon stereocenters is a significant challenge in asymmetric synthesis.Catalytic synthesis of these structures with trisubstituted allylic alcohols is highly important. However, ...
the National Natural Science Foundation of China(22071112 and 22275098);the Project of State Key Laboratory of Organic Electronics and Information Displays,Nanjing University of Posts and Telecommunications(GDX2022010005 and GZR2022010011);the Postgraduate Technology&Practice Innovation Program of Jiangsu Province(KYCX22_0902).
To address the stereoselective synthesis challenge inπ-stacked grids with four chiral centers,we utilized coplanar and highly rigid 11,12-dihydroindeno[2,1-a]fluorene-11,12-diol and 2,2'-bithiophene as synthons,emplo...
the financial support from the National Natural Science Foundation of China(21801129,22078153 and 22378201);National Key Research and Development Program of China(2022YFB3805603);Natural Science Research Projects in Jiangsu Higher Education Institutions(18KJB150018);Nanjing Tech University(Start-up Grant Nos.39837137,39837101 and 3827401739)for financial support.
A visible-light-induced photoredox-catalyzed regioselective and stereoselective C(sp')-H amination of enamides with bench-stable and A visible-light-induced photoredox-catalyzed regioselective and stereoselective C(sp...
the National Science Foundation of China(grant nos.22031003 and 21720102004);the Shanghai Science Technology Committee,China(grant no.19DZ2270100);the Shanghai Post-doctoral Excellence Program,China(grant no.2022009).
Designing and stereoselectively constructing chiral mechanically interlocked molecules(MIMs)is a goal that many chemists are pursuing due to their potential in the development of functional molecular machines involved...
supports from National Natural Science Foundation of China(22322110);the CAS Pioneer Hundred Talents Program(No.2017-128);Yunnan Province Science and Technology Department(202305AH340005);the Young Talents Project of High-level Talent Introduction Program of Yunnan Province are greatly acknowledged。
Collective syntheses of A.baumannii CPS K43,K47 and K88 repeating units have been accomplished via a newα-glycosylation method with GlcN_(3) as donors,which features:1)mild reaction conditions,2)good to high yields,3...
supported by the National Natural Science Foundation of China(Nos.21961048 and 32271537);Science and Technology Department of Zunyi(Nos.ZSKRPT-2020-5,ZSKH-2018-3 and ZSKRPT-2021-5).
Chiral methyl mandelates are useful synthons in organic transformation and pharmaceutical synthesis.Green synthesis of these valuable compounds by direct C–H activating oxidative hydroxylation has attracted keen inte...
supported by the Recruitment Program of Global Experts of China,the National Natural Science Foundation of China(Nos.21602028 and 22371240);Beijing National Laboratory for Molecular Sciences(No.BNLMS201913);100-Talent program of Fujian,Fuzhou University and Xiamen University.
The tacticity of vinyl polymers is a key factor affecting the properties of materials.Recently,organic Brønsted acids have been demonstrated as effective catalysts for the development of highly stereoselective cationi...
supported by the National Natural Science Foundation of China (22071111);the Jiangsu Specially Appointed Professor Plan;the Natural Science Foundation of Jiangsu Province(BK20201368, BK20220409);the Postgraduate Research&Practice Innovation Program of Jiangsu Province (KYCX23_1683)。
1,3-Diene architectures are not only widely present in natural products, pharmaceuticals, and functional organic materials but also serve as versatile building blocks to furnish important functionalized molecules in s...