the financial support from the National Natural Science Foundation of China(21801129,22078153 and 22378201);National Key Research and Development Program of China(2022YFB3805603);Natural Science Research Projects in Jiangsu Higher Education Institutions(18KJB150018);Nanjing Tech University(Start-up Grant Nos.39837137,39837101 and 3827401739)for financial support.
A visible-light-induced photoredox-catalyzed regioselective and stereoselective C(sp')-H amination of enamides with bench-stable and A visible-light-induced photoredox-catalyzed regioselective and stereoselective C(sp...
supported by the National Natural Science Foundation of China(No.22001248);the Fundamental Research Funds for the Central Universities and University of Chinese Academy of Sciences.
A charge transfer complex(CTC)-enabled photoreduction of ether phosphonium salts for the generation of oxyalkyl radicals was described.The photoreduction provides a convenient method to achieve selective oxyalkylation...
financially supported by National Key R&D Program of China(2022 YFD1400700);the Natural Science Foundation of Fujian Province of China(2020J01526);the Foundation of Education Department of Fujian Province of China(JAT21006);the Foundation of Key Laboratory of Biopesticide and Chemical Biology(Keylab2020-03).
On the basis of the structure of natural product lansiumamide B(1),a total of 27 novel cis-enamide compounds were designed and synthesized via Intermediate Derivatization Method.Their chemical structures were characte...
We gratefully acknowledge the National Natural Science Foundation of China(22122103,22101130,22001116,21971108,21971111,21732003);the National Key Research and Development Program of China(2021YFC2101901);the Fundamental Research Funds for the Central Universities(020514380252);the Natural Science Foundation of Jiangsu Province(Grant No.BK20190006);the Guangdong Basic and Applied Basic Research Foundation(2020A1515110816);the"Innovation&Entrepreneurship Talents Plan"of Jiangsu Province.Nian Li,Chuan-Gang Zhao,Junheng Liu are warmly acknowledged to reproduce experimental procedures for products 3ii,5p and 3a.
The arylethylamine framework is a prevalent motif in a great range of biologically important organic compounds.One intractable task for frontline drug discovery is to find structurally new medicine candidates instead ...
Financial support from the National Natural Science Foundation of China(21931013);Guangdong Provincial Key Laboratory of Catalysis(No.2020B121201002);the Open Research Fund of School of Chemistry and Chemical Engineering,Henan Normal University is gratefully acknowl-edged.
1,3-Oxazin-6-ones as important structural scaffolds widely exist in many bioactive or therapeutic agents.The development of straightforward synthetic approaches to access 1,3-oxazin-6-ones is highly desirable for stud...
the National Natural Science Foundation of China(grant nos.21971204 and 21622203);the Innovation Capability Support Program of Shaanxi Province(grant no.2020TD-022).
A catalytic,enantioselective spirocyclization of formanilides or formylindolines and enamides has been developed herein.The reaction proceeds through a sequential iridium-catalyzed hydrosilylation of tertiary formanil...
the National Natural Science Foundation of China(No.21702106);the Natural Science Foundation of Jiangsu Province(No.BK20170967);the Start-up Grant from Nanjing Tech University(No.39839101)for financial support。
Disclosed herein is an efficient Ag-catalyzed 4+1 heteroannulation reaction of enamides withα-carbonyl sulfoxonium ylides.The diastereoselective transformation provides a practical access to a diverse range of multi-...
supported by the National Natural Science Foundation of China (NSFC-21622203, 21472147, 21702161);the China Postdoctoral Science Foundation Funded Project (2017M610644);Fund of Northwest University (334100036)
A novel palladium-catalyzed oxidative cyclopropanation of enamides and norbornenes has been developed. The reaction proceeded through palladium-catalyzed vinyl C–H bond activation of enamides followed by two migrator...
Herein, we report a novel synthesis of 1,3-oxazin-6-ones from enamides with CO2 through C--H carboxylation and one-pot cyclization. This transition-metal-free and redox-neutral process features broad substrate scope, ...
We gratefully acknowledge financial support from the National Natural Science Foundation of China (Nos. 21572217, 21402184, 21172213, and 21302109).
A simple and convenient copper-catalyzed direct oxyphosphorylation of enamides with P(O)-H compounds and dioxygen has been developed under mild conditions. This methodology can allow the synthesis of a series of val...