PALLADIUM-CATALYZED

作品数:171被引量:138H指数:6
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相关领域:理学更多>>
相关作者:吴养洁崔秀灵张浩刘秀艳龙蓉蓉更多>>
相关机构:郑州大学南开大学辽宁石油化工大学中国人民大学更多>>
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相关基金:国家自然科学基金国家重点基础研究发展计划广东省自然科学基金国家教育部博士点基金更多>>
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Efficient Construction of Chiral Binaphthalene-Core Phosphepine Compounds Using Palladium-Catalyzed C—P Coupling Reactions
《有机化学》2024年第12期3771-3783,共13页Wang Cuiying Zhang Ying Zheng Jia-Lian Yuan Ji Meng Sixuan Chen Jian Yu Guang-Ao 
国家自然科学基金(Nos.22371084,21072071,21472060,21772058);高等学校学科创新引智计划(111计划,No.B17019);华中师范大学中央高校基本科研业务费专项资金(Nos.CCNU17CG0011,CCNU17KYZHSY07,CCNU18KYZHSY06)资助项目.
Binaphthalene-core phosphepine compounds with axial chirality belong to an important class of organocatalysts and ligands used in catalytic asymmetric synthesis.However,the number and application of these compounds ha...
关键词:Pd catalysis chiral axially BINAPHTHALENE C-P coupling reactions 
Palladium-Catalyzed Direct B—H Oxygenation:Facile Synthesis of o-Carboranofuranones
《Chinese Journal of Chemistry》2024年第23期3083-3087,共5页Chenyang Guo Zaozao Qiu Zuowei Xie 
supported by the grants from the National Natural Science Foundation of China(Project Nos.22371290 and 92056106 to Z.Q.,Project No.22331005 to Z.X.);Shenzhen Science and Technology Program(Project No.QTD20221101093558015 to Z.X.);the Shanghai-Hong Kong Joint Laboratory in Chemical Synthesis,CAS.
Recent advances in transition metal-catalyzed o-carborane B—H activation have led to the rapid development of various methodologies for cage boron functionalization.For catalytic cage B—H acyloxylation,intermolecula...
关键词:CARBORANE B-H activation OXYGENATION Catalysis Transition metal Palladium Cross-coupling Regioselectivity 
Palladium-catalyzed enantioselective decarboxylation of vinyl cyclic carbamates:Generation of amide-based aza-1,3-dipoles and application to asymmetric 1,3-dipolar cycloaddition
《Chinese Chemical Letters》2024年第12期454-461,共8页Xiaohui Fu Yanping Zhang Juan Liao Zhen-Hua Wang Yong You Jian-Qiang Zhao Mingqiang Zhou Wei-Cheng Yuan 
the National Natural Science Foundation of China(Nos.22271027,22171029,21901024,21871252,21801024,and 21801026);the Sichuan Science and Technology Program(No.2021YFS0315);the Talent Program of Chengdu University(Nos.2081919035 and 2081921038)。
The catalytic asymmetric dipolar cycloaddition reaction is efficient for the construction of various chiral valuable carbo-and heterocycles.Thus,the design and exploration of new dipoles and the subsequent control of ...
关键词:CYCLOADDITION Palladium ENANTIOSELECTIVITY Asymmetric catalysis DECARBOXYLATION 
Palladium-catalyzed vinylation of indoles with vinyl ethers via deoxygenative coupling
《Science China Chemistry》2024年第11期3785-3790,共6页Bowen Wang Jianxiao Li Wanqing Wu Liangbin Huang Huanfeng Jiang 
supported by the National Key Research and Development Program of China (2022YFB4101800);the National Natural Science Foundation of China (22231002);the Guangdong Basic and Applied Basic Research Foundation (2024B1515040027)。
Indole is a promising heteroarene in many natural products and pharmaceuticals;therefore, various synthetic methods for indole functionalizations have arisen in recent years. Herein, we report a Pd-catalyzed deoxygena...
关键词:INDOLE VINYLATION regioselectivity N-vinyl indole palladium catalyst 
Palladium-catalyzed dicarbonylation of 1,3-butadiene with bidentate phosphine ligands:A density functional theory study
《Chinese Journal of Chemical Engineering》2024年第10期92-99,共8页Zhongxian Yu Jianhua Song Dianhua Liu 
DFT calculations have been performed to discover the mechanism for the synthesis of dimethyl adipate(DMA)by 1,3-butadiene(BD)dicarbonylation catalyzed by a complex consisting of palladium and a bidentate diphosphine l...
关键词:1 3-BUTADIENE Dicarbonylation DTBPX DFT Catalytic cycle 
Palladium-Catalyzed Selective Syntheses of 2,3-Allenyl Amines via Double Functionalization Coupling of 2-Alkynyl-1,4-diol Dicarbonates
《Chinese Journal of Chemistry》2024年第19期2357-2362,共6页Zhengnan Zhou Can Li Shengming Ma 
National Natural Science Foundation of China(No.21988101)is greatly appreciated.
Comprehensive Summary 2,3-Allenyl amines have shown wide applicability in biomedical and synthetic applications.Due to their enormous potential for applications,researchers have been dedicated to the development of me...
关键词:Pd catalysis 2 3-Allenyl amine Alk-2-yn-1 4-diol dicarbonate Organoboronic acid 1 2 3-Triene Methylene-π-allyl palladium species Regioselectivity CHEMOSELECTIVITY 
Palladium-catalyzed oxidative double alkoxycarbonylation of ethylene toward succinic acid derivatives
《Green Carbon》2024年第2期205-208,共4页Zhi-Peng Bao Cunyao Li Li Yan Yunjie Ding Xiao-Feng Wu 
support from National Key R&D Program of China(2023YFA1507500)and DICP.
Employing biodegradable plastics is one of the choices to solve white pollution issues.Polybutylene succinate(PBS),as a biodegradable plastic with good stability and heat resistance,is produced by polymerization of su...
关键词:ETHYLENE ALCOHOLS Palladium CARBONYLATION Succinic acid derivatives 
Palladium-catalyzed carbonylation of activated alkyl halides via radical intermediates
《Industrial Chemistry & Materials》2024年第2期276-283,共8页Zhi-Peng Bao Xiao-Feng Wu 
financial support from DICP and K.C.Wong Education Foundation(GJTD-2020-08).
Palladium-catalyzed carbonylation is an efficient approach to prepare carbonyl-containing compounds with high atomic economy in synthetic organic chemistry.However,in comparison with aryl halides,carbonylation of alky...
关键词:Carbonyl group Palladium catalysis CARBONYLATION Activated alkyl halides Radical intermediates 
Palladium-Catalyzed[4+2]and[6+2]Dipolar Cycloadditions for the Construction of Benzo[d]isothiazole 1,1-Dioxide Fused 1,3-Oxazinanes and 1,3-Oxazocanes
《Chinese Journal of Chemistry》2024年第8期829-834,共6页Lei Chen Hongling Xie Yu Xue Zhengyu Han Jianwei Sun Hai Huang 
supported by the NSFC(22071210,22101033,22201023,22271242);the Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology(BM2012110);the Natural Science Foundation of Jiangsu Province(BK20210849);the Innovation&Entrepreneurship Talents Plan of Jiangsu Province(JSSCRC2021536).
Comprehensive Summary,The Pd-catalyzed dipolar cycloaddition represents a significant synthetic strategy for the construction of useful heterocyclic compounds.This study developed the dipolar[4+2]and[6+2]cycloaddition...
关键词:Cycloaddition 1 3-Oxazinanes 1 3-Oxazocanes Medium-ring compounds STEREOCHEMISTRY N-HETEROCYCLES SULFONAMIDES ENANTIOSELECTIVITY Asymmetricsynthesis 
Palladium-catalyzed S_(N)2 glycosylation of phenols
《Science China Chemistry》2024年第4期1037-1038,共2页Yu Zhu P.Andrew Evans 
Glycosides are essential structural motifs present in an array of important medicines,materials,and natural products[1].Nevertheless,the chemo-and stereoselective construction of the glycosidic linkage is a long-stand...
关键词:PROPERTIES PALLADIUM CATALYZED 
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