Binaphthalene-core phosphepine compounds with axial chirality belong to an important class of organocatalysts and ligands used in catalytic asymmetric synthesis.However,the number and application of these compounds ha...
supported by the grants from the National Natural Science Foundation of China(Project Nos.22371290 and 92056106 to Z.Q.,Project No.22331005 to Z.X.);Shenzhen Science and Technology Program(Project No.QTD20221101093558015 to Z.X.);the Shanghai-Hong Kong Joint Laboratory in Chemical Synthesis,CAS.
Recent advances in transition metal-catalyzed o-carborane B—H activation have led to the rapid development of various methodologies for cage boron functionalization.For catalytic cage B—H acyloxylation,intermolecula...
the National Natural Science Foundation of China(Nos.22271027,22171029,21901024,21871252,21801024,and 21801026);the Sichuan Science and Technology Program(No.2021YFS0315);the Talent Program of Chengdu University(Nos.2081919035 and 2081921038)。
The catalytic asymmetric dipolar cycloaddition reaction is efficient for the construction of various chiral valuable carbo-and heterocycles.Thus,the design and exploration of new dipoles and the subsequent control of ...
supported by the National Key Research and Development Program of China (2022YFB4101800);the National Natural Science Foundation of China (22231002);the Guangdong Basic and Applied Basic Research Foundation (2024B1515040027)。
Indole is a promising heteroarene in many natural products and pharmaceuticals;therefore, various synthetic methods for indole functionalizations have arisen in recent years. Herein, we report a Pd-catalyzed deoxygena...
DFT calculations have been performed to discover the mechanism for the synthesis of dimethyl adipate(DMA)by 1,3-butadiene(BD)dicarbonylation catalyzed by a complex consisting of palladium and a bidentate diphosphine l...
National Natural Science Foundation of China(No.21988101)is greatly appreciated.
Comprehensive Summary 2,3-Allenyl amines have shown wide applicability in biomedical and synthetic applications.Due to their enormous potential for applications,researchers have been dedicated to the development of me...
support from National Key R&D Program of China(2023YFA1507500)and DICP.
Employing biodegradable plastics is one of the choices to solve white pollution issues.Polybutylene succinate(PBS),as a biodegradable plastic with good stability and heat resistance,is produced by polymerization of su...
financial support from DICP and K.C.Wong Education Foundation(GJTD-2020-08).
Palladium-catalyzed carbonylation is an efficient approach to prepare carbonyl-containing compounds with high atomic economy in synthetic organic chemistry.However,in comparison with aryl halides,carbonylation of alky...
supported by the NSFC(22071210,22101033,22201023,22271242);the Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology(BM2012110);the Natural Science Foundation of Jiangsu Province(BK20210849);the Innovation&Entrepreneurship Talents Plan of Jiangsu Province(JSSCRC2021536).
Comprehensive Summary,The Pd-catalyzed dipolar cycloaddition represents a significant synthetic strategy for the construction of useful heterocyclic compounds.This study developed the dipolar[4+2]and[6+2]cycloaddition...
Glycosides are essential structural motifs present in an array of important medicines,materials,and natural products[1].Nevertheless,the chemo-and stereoselective construction of the glycosidic linkage is a long-stand...