Palladium-catalyzed oxidative double alkoxycarbonylation of ethylene toward succinic acid derivatives  

作　　者：Zhi-Peng Bao Cunyao Li Li Yan Yunjie Ding Xiao-Feng Wu 

机构地区：[1]Dalian National Laboratory for Clean Energy,Dalian Institute of Chemical Physics,Chinese Academy of Sciences,Dalian,Liaoning 116023,China [2]Leibniz-Institut für Katalyse e.V.,Rostock 18059,Germany

出　　处：《Green Carbon》2024年第2期205-208,共4页绿碳（英文）

基　　金：support from National Key R&D Program of China(2023YFA1507500)and DICP.

摘　　要：Employing biodegradable plastics is one of the choices to solve white pollution issues.Polybutylene succinate(PBS),as a biodegradable plastic with good stability and heat resistance,is produced by polymerization of succinic acid and butylene glycol.However,inadequate supply of the direct upstream material succinic acid restricts the development of this industry.In this work,we provide a carbonylative strategy to construct succinic acid derivatives from carbon monoxide(CO),ethylene and alcohols.The reaction catalyzed by palladium catalyst under oxidative conditions.

关 键 词：ETHYLENE ALCOHOLS Palladium CARBONYLATION Succinic acid derivatives 

分 类 号：O64[理学—物理化学]