1,3-BUTADIENE

作品数:42被引量:37H指数:3
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相关领域:理学更多>>
相关作者:李占杰张文雄刘倩李伟李天宇更多>>
相关机构:北京大学中国科学院中国科学技术大学大连理工大学更多>>
相关期刊:《Chinese Journal of Polymer Science》《Chinese Journal of Structural Chemistry》《分子科学学报》《Journal of Energy Chemistry》更多>>
相关基金:国家自然科学基金国家重点基础研究发展计划中国博士后科学基金王宽诚敎育基金更多>>
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Identifying a bi-molecular synergetic adsorption mechanism for catalytic transformation of ethanol/acetaldehyde into 1,3-butadiene
《Chinese Journal of Catalysis》2025年第4期297-307,共11页Xianquan Li Jifeng Pang Yujia Zhao Lin Li Wenguang Yu Feifei Xu Yang Su Xiaofeng Yang Wenhao Luo Mingyuan Zheng 
国家自然科学基金(22378383);国家自然科学基金单原子催化基础研究中心(22388102);中国科学院战略重点研究项目“清洁能源转化技术与示范”(XDA 21060200).
The catalytic synthesis of 1,3-butadiene(1,3-BD)from bio-based ethanol offers an alternative and sustainable process beyond petroleum.However,the intrinsic active sites and corresponding mechanism of 1,3-BD formation ...
关键词:1 3-BUTADIENE Bi-molecular Co-adsorption-mechanism Reaction mechanism Ethanol conversion 
Iminopyridine Manganese and Nickel Complexes:Synthesis,Characterization and Behavior in the Polymerization of 1,3-Butadiene
《Chinese Journal of Polymer Science》2025年第1期83-89,I0008,共8页Giovanni Ricci Benedetta Palucci Simona Losio Anna Sommazzi Francesco Masi Guido Pampaloni Massimo Guelfi 
Some novel manganese and nickel complexes were synthesized by reacting manganese(Ⅱ) dichloride and nickel(Ⅱ) dichloride with pyridyl-imine ligands differing in the nature of the substituents at the imino nitrogen at...
关键词:MANGANESE NICKEL CATALYSTS POLYMERIZATION POLYBUTADIENE X-ray structures 
Palladium-catalyzed dicarbonylation of 1,3-butadiene with bidentate phosphine ligands:A density functional theory study
《Chinese Journal of Chemical Engineering》2024年第10期92-99,共8页Zhongxian Yu Jianhua Song Dianhua Liu 
DFT calculations have been performed to discover the mechanism for the synthesis of dimethyl adipate(DMA)by 1,3-butadiene(BD)dicarbonylation catalyzed by a complex consisting of palladium and a bidentate diphosphine l...
关键词:1 3-BUTADIENE Dicarbonylation DTBPX DFT Catalytic cycle 
Applying an AIE type fluorescent probe in the detection of tetracycline antibiotics
《分子科学学报》2024年第2期146-152,共7页HU Bo ZHENG Luying WANG Rui XU Kun ZHAO Sisi YU Zhan CHEN Qingyang ZHANG Hang 
supported by the National Natural Science Foundation of China(22109105,22102106);Innovation Entrepreneurship Training Program for College Students of the School of Chemistry and Chemical Engineering at Shenyang Normal University
The typical representative TPB(tetraphenyl-1,3-butadiene)molecule with AIE effect was used as a fluorescent probe,and the specific recognition of tetracycline antibiotics was achieved through the comparison of the exp...
关键词:fluorescence detection technology tetraphenyl-1 3-butadiene tetracycline antibiotics 
Polymerization of 1,3-Butadiene with Catalysts Based on Cobalt Dichloride Complexes with Aminophosphines: Switching the Regioselectivity by Varying the MAO/Co Molar Ratio
《Chinese Journal of Polymer Science》2024年第4期501-510,共10页Giovanni Ricci Anna Sommazzi Francesco Masi Alessandra Forni 
Several novel cobalt dichloride complexes with amino-phosphine bidentate ligands were synthesized and characterized.For some of them single crystals were obtained and their molecular structure was determined by X-ray ...
关键词:1 3-BUTADIENE Stereospecific polymerization Cobalt catalysts Regioselectivity Aminophosphine ligands Crystal structures Chelate rings 
Industrially applied and relevant transformations of 1,3-butadiene using homogeneous catalysts
《Industrial Chemistry & Materials》2023年第2期155-174,共20页Ji Yang Peng Wang Helfried Neumann Ralf Jackstell Matthias Beller 
In recent decades,the use of 1,3-butadiene as a comparably cheap and abundant raw material for new applications has attracted more and more interest,specifically in the chemical industry.The present review covers seve...
关键词:1 3-BUTADIENE Industrial chemistry Carbonylation reaction Bulk chemicals Telomerization. 
Hydroxyl Group-Enabled Highly Efficient Ligand for Pd-Catalyzed Telomerization of 1,3-Butadiene with CO_(2)
《Chinese Journal of Chemistry》2022年第23期2734-2740,共7页Zhengyi Yang Chaoren Shen Kaiwu Dong 
supported by the National Key R&D Program of China(No.2020YFA0710201);the Science and Technology Commission of Shanghai Municipality(20ZR1471400);the Shanghai Rising Star Program(21QA1402800);the Fundamental Research Funds for the Central Universities.
By introducing hydroxyl group into PPh3 ligand,a promoter-free palladium catalytic system based on(p-HOC6H4)PPh2 ligand was developed for the telomerization of 1,3-butadiene with CO_(2).High activity and selectivity t...
关键词:Carbon dioxide fixation TELOMERIZATION 1 3-Butadiene LACTONES PALLADIUM 
Highly Efficient and Thermal Robust Cobalt Complexes for 1,3-Butadiene Polymerization被引量:2
《Chinese Journal of Polymer Science》2022年第11期1369-1379,共11页Liang Fang Wen-Peng Zhao Chun-Yu Zhang Xue-Quan Zhang Xian-De Shen Heng Liu Toyoji Kakuchi 
financially supported by the National Natural Science Foundation of China(Nos.U1862206 and 21801236)。
A family of highly bulky bis(salicylaldiminate)Co(Ⅱ)complexes bearing cavity-like conformations are disclosed herein.Due to their unique bulky nature around the cobalt atoms that are reflected from space-filling mode...
关键词:Butadiene polymerization Bis(salicylaldiminate)Co(Ⅱ)complexes Ultra high catalytic efficiency 
Reaction Mechanism of One-Step Conversion of Ethanol to 1,3-Butadiene over Zn-Y/BEA and Superior Catalysts Screening被引量:2
《Chinese Journal of Chemical Physics》2022年第4期600-610,I0004-I0009,I0149,共18页Shu-Xuan Dang Han-Xuan Liu Tao Ban Xin Gao Zheng-Qing Huang Dong-Yuan Yang Chun-Ran Chang 
This work was supported by the National Natural Science Foundation of China(No.22078257,No.22038011,and No.22108213);the National Key R&D Program of China(No.2020YFA0710000);the China Postdoctoral Science Foundation(No.2018T111034 and No.2021M692548);the Rising Star Program in Science and Technology of Shaanxi Province(No.2020KJXX-079).Chun-Ran Chang also acknowledges the support from the K.C.Wong Education Foundation.The calculations were performed by using the HPC Platform at Xi’an Jiaotong University。
The one-step conversion of ethanol to 1,3-butadiene has achieved a breakthrough with the development of beta zeolite supported dual metal catalysts.However,the reaction mechanism from ethanol to butadiene is complex a...
关键词:ETHANOL 1 3-BUTADIENE Zn-Y/BEA Aldol condensation Density functional theory 
Selective hydrogenation of 1,3-butadiene on iridium nanostructures:Structure sensitivity, host effect, and deactivation mechanism
《Journal of Energy Chemistry》2022年第6期541-554,I0015,共15页Mengru Wang Yuxue Yue Yi Wang Xiaoling Mou Renqin Chang Zupeng Chen Ronghe Lin Jia Zhao Yunjie Ding 
Zhejiang Normal University for providing the financial support (YS304320035, YS304320036, ZZ323205020521005039);Financial support from the National Natural Science Foundation of China (NSFC, 21606199);the Science and Technology Department of Zhejiang Province (LGG20B060004);the National Key Research and Development Program of China (2021YFA1501800, 2021YFA1501801, 2021YFA1501802) are also gratefully acknowledged。
A systematic study on the structure sensitivity,host effect,and the deactivation mechanism of Ircatalyzed selective hydrogenation of 1,3-butadiene,a key process in the purification of alkadiene for the upgrading of C4...
关键词:1 3-Butadiene DEACTIVATION HYDROGENATION IRIDIUM Nitrogen-doped carbon Structure sensitivity 
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