Some novel manganese and nickel complexes were synthesized by reacting manganese(II)dichloride and nickel(II)dichloride with pyridyl-imine ligands differing in the nature of the substituents at the imino nitrogen atom...
DFT calculations have been performed to discover the mechanism for the synthesis of dimethyl adipate(DMA)by 1,3-butadiene(BD)dicarbonylation catalyzed by a complex consisting of palladium and a bidentate diphosphine l...
supported by the National Natural Science Foundation of China(22109105,22102106);Innovation Entrepreneurship Training Program for College Students of the School of Chemistry and Chemical Engineering at Shenyang Normal University
The typical representative TPB(tetraphenyl-1,3-butadiene)molecule with AIE effect was used as a fluorescent probe,and the specific recognition of tetracycline antibiotics was achieved through the comparison of the exp...
Several novel cobalt dichloride complexes with amino-phosphine bidentate ligands were synthesized and characterized.For some of them single crystals were obtained and their molecular structure was determined by X-ray ...
In recent decades,the use of 1,3-butadiene as a comparably cheap and abundant raw material for new applications has attracted more and more interest,specifically in the chemical industry.The present review covers seve...
supported by the National Key R&D Program of China(No.2020YFA0710201);the Science and Technology Commission of Shanghai Municipality(20ZR1471400);the Shanghai Rising Star Program(21QA1402800);the Fundamental Research Funds for the Central Universities.
By introducing hydroxyl group into PPh3 ligand,a promoter-free palladium catalytic system based on(p-HOC6H4)PPh2 ligand was developed for the telomerization of 1,3-butadiene with CO_(2).High activity and selectivity t...
financially supported by the National Natural Science Foundation of China(Nos.U1862206 and 21801236)。
A family of highly bulky bis(salicylaldiminate)Co(Ⅱ)complexes bearing cavity-like conformations are disclosed herein.Due to their unique bulky nature around the cobalt atoms that are reflected from space-filling mode...
This work was supported by the National Natural Science Foundation of China(No.22078257,No.22038011,and No.22108213);the National Key R&D Program of China(No.2020YFA0710000);the China Postdoctoral Science Foundation(No.2018T111034 and No.2021M692548);the Rising Star Program in Science and Technology of Shaanxi Province(No.2020KJXX-079).Chun-Ran Chang also acknowledges the support from the K.C.Wong Education Foundation.The calculations were performed by using the HPC Platform at Xi’an Jiaotong University。
The one-step conversion of ethanol to 1,3-butadiene has achieved a breakthrough with the development of beta zeolite supported dual metal catalysts.However,the reaction mechanism from ethanol to butadiene is complex a...
Zhejiang Normal University for providing the financial support (YS304320035, YS304320036, ZZ323205020521005039);Financial support from the National Natural Science Foundation of China (NSFC, 21606199);the Science and Technology Department of Zhejiang Province (LGG20B060004);the National Key Research and Development Program of China (2021YFA1501800, 2021YFA1501801, 2021YFA1501802) are also gratefully acknowledged。
A systematic study on the structure sensitivity,host effect,and the deactivation mechanism of Ircatalyzed selective hydrogenation of 1,3-butadiene,a key process in the purification of alkadiene for the upgrading of C4...
This work was supported by the National Natural Science Foundation of China(no.U2032132).
Chemically recyclable solid polymeric materials with commercializable properties only using CO_(2)and inexpensive bulk chemicals as chemical feedstock can open a brand-new avenue to economically viable,large-scale fix...