ISOCYANIDES

作品数：21被引量：12H指数：2
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相关领域：理学化学工程更多>>
相关作者：许斌于杨王浩解春松毛宏更多>>
相关机构：上海大学杭州师范大学东北师范大学苏州大学更多>>
相关期刊：《Science China Chemistry》《Science Bulletin》《Green Synthesis and Catalysis》《Organic Chemistry Frontiers》更多>>
相关基金：国家自然科学基金上海市教育委员会创新基金国家重点实验室开放基金中国博士后科学基金更多>>
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[1,2]-Phospha-Brook Rearrangement-Initiated Palladium-Catalyzed Cyclization Reaction of Isocyanides and o-Bromobenzaldehydes:Access to 2H-Isoindole-1-carboxamides and 2H-Isoindole-1-carbonitriles
《Chinese Journal of Chemistry》2025年第6期620-626,共7页Binbin Wang Qiushan Gao Huanfeng Jiang Wanqing Wu 
financially supported by the National Natural Science Foundation of China(22071063);National Youth Talent Support Program,Guangdong Basic and Applied Basic Research Foundation(2021B1515020058 and 2024B1515040027);Guangzhou Science and Technology Projects(2024A04J6248).
Comprehensive Summary Herein,a[1,2]-phospha-Brook rearrangement-initiated palladium-catalyzed cyclization reaction for base-controlled selective synthesis of 2H-isoindole-1-carboxamide and 2H-isoindole-1-carbonitrile ...
关键词：PALLADIUM-CATALYZED Cyclization[1 2]-Phospha-Brook rearrangement ISOCYANIDES Insertion Heterocycles 
Catalyst-Free, Radical Tri- and Difluoromethylation of Isocyanides and N-Arylacrylamides Using Rotating Magnetic Field and Metal Rods
《Chinese Journal of Chemistry》2025年第2期155-160,共6页Xuliang Han Haodong Liu Xiaomei Feng Fuchao Jia Zengdian Zhao Xinjin Li 
support by the National Natural Science Foundation of China(22101157)is gratefully acknowledged;We are very grateful to Prof.Xiao Shen(Wuhan University,China)for helpful discussion.
The pursuit of sustainable and environmentally benign synthetic methods continues to challenge organic chemists. Herein, we introduce a magnetoredox system for tri- and difluoromethylation of isocyanides and N-arylacr...
关键词：TRIFLUOROMETHYLATION DIFLUOROMETHYLATION Radical Single-electron transfer CATALYST-FREE Magnetic field Electromagnetic induction ISOCYANIDES 
Base-controlled annulation of tryptamine-derived isocyanides with nitrile imines for access to polycyclic spiroindoline derivatives
《Green Synthesis and Catalysis》2023年第2期181-185,共5页Xiaofeng Wang Luorong Yuan Xiaoping Xu Shunjun Ji 
the National Natural Science Foundation of China(Nos.21772138 and 21672157);the Natural Science Foundation of Jiangsu Province,the Project of the Scientific and Technologic Infrastructure of Suzhou(No.SZS201708)and PAPD.
An annulation reaction of tryptamine-derived isocyanides with hydrazonyl chlorides in the presence of bases was developed.Controlled by different bases,[1+2+3]annulation and[1+2+3]/[2+3]annulation cascade were realize...
关键词：3-(2-Isocyanoethyl)indoles Nitrile imines Tetracyclic spiroindolines Pentacyclic bispiroindolines Chemoselective cycloaddition 
[4+3]Cycloaddition of ketenimines with furocarbenoids:Divergent and efficient synthesis of fused cycloheptatriene and tropone scaffolds
《Chinese Chemical Letters》2023年第5期227-231,共5页Jin Wang Zhaoyang Li Shengxin Bai Qinghua Zhou Tengteng Wu Zhongyan Hu Xianxiu Xu 
financial support from National Natural Science Foundation of China(Nos.22171168,22001152 and 22101159);Taishan Scholar Program of Shandong Province and the Natural Science Foundation of Shandong Province of China(No.ZR2020QB019)。
An unprecedent[4+3]cycloaddition of furoketenimines with furocarbenoids has been disclosed for the divergent and efficient synthesis of cycloheptafuran and cycloheptapyrrole scaffolds.Zinc chloride acted as promoters ...
关键词：Domino reactions ISOCYANIDES Ene-yne-ketones Cycloheptafuran scaffolds [4+3]cycloaddition 
Copper-catalyzed chemoselective heterocyclization of two isocyanides:Facile access to pyrroloazepinone derivatives
《Chinese Chemical Letters》2023年第2期202-205,共4页Xiaoyu Guo Jinhuan Dong Yunjie Zhu Lan Bao Zhongyan Hu Xianxiu Xu 
Financial support from the National Natural Science Foundation of China (Nos. 22001151, 22171168, 22101159);Taishan Scholar Program of Shandong Province and Shandong Provincial Natural Science Foundation (Nos. ZR2019QB004, ZR2020QB019) is gratefully acknowledged。
A Cu-catalyzed chemoselective heterocyclization of o-cinnamoyl arylisocyanides with α-substituted tosylmethyl isocyanides is developed for the efficient synthesis benzopyrroloazepinones. An isocyanide insertion into ...
关键词：ISOCYANIDES Domino reactions Pyrroloazepinones 
Palladium-catalyzed cyclization of 1-alkynyl-8-iodonaphthalene and double isocyanides for the synthesis of acenaphtho[1,2-b]pyrroles被引量：1
《Chinese Chemical Letters》2022年第11期4870-4873,共4页Shangfeng Ren Keke Huang Jin-Biao Liu Lianpeng Zhang Min Hou Guanyinsheng Qiu 
Financial supports from the Natural Science Foundation of Zhejiang Province(No.LY22B020010);the National Natural Science Foundation of China(Nos.21772067,21801096 and 22161043);The Youth Jinggang Scholars Program in Jiangxi Province。
A palladium-catalyzed formal[2+2+1]cyclization of 1-alkynyl-8-iodonaphthalene with double isocyanides is developed herein.The transformation worked well to produce a series of 7 H-acenaphtho[1,2-b]pyrrole with a broad...
关键词：[2+2+1]Cyclization ISOCYANIDES Palladium catalysis ALKYNE PYRROLE 
Rhodium-catalyzed coupling-cyclization reaction of isocyanides and 2-azidophenyloxyacrylates:synthesis of N-(3-substituted benzo[d]oxazol-2(3H)-ylidene)amines and dihydrobenzo[d]oxazoles被引量：1
《Organic Chemistry Frontiers》2022年第2期407-412,共6页Ming Yang Xue-Cen Xu Yue Gong Yu-Long Zhao 
Financial support of this research by the National Natural Science Foundation of China(21871044 and 21472017);the Natural Science Foundation of Jilin Province(20190201073JC)is greatly acknowledged.
A rhodium-catalyzed coupling cyclization of isocyanides with 2-azidophenyloxyacrylates has been developed for the first time.This reaction allows divergent syntheses of two significant N-heterocycles,fivemembered N-(3...
关键词：SUBSTITUTED CATALYZED AMINES 
One-pot two-step reaction of selenosulfonate with isocyanides and allyl alcohol under aqueous conditions:Atom-economic synthesis of selenocarbamates and allyl sulfones被引量：1
《Chinese Chemical Letters》2021年第2期721-724,共4页Jing-Jing Ai Jian Li Shun-Jun Ji Shun-Yi Wang 
the National Natural Science Foundation of China (Nos.21971174,21772137,21672157);the Ph.D.Programs Foundation of PAPD;the Project of Scientific and Technologic Infrastructure of Suzhou (No.SZS201708);the Major Basic Research Project of the Natural Science Foundation of the Jiangsu Higher Education Institutions (No. 16KJA150002);Soochow University,and State and Local Joint Engineering Laboratory for Novel Functional Polymeric Materials for financial support。
In many reactions involving selenosulfonate or thiosulfonate,the sutfone group often leaves in form of benzenesutfinic acid or sodium benzenesulfinate.A one-pot two-step reaction of selenosulfonate with isocyanides an...
关键词：Aqueous conditions One-pot two-step process Benzenesulfinic acid Selenocarbamate Allyl sulfone compound 
Palladium-catalyzed concerted [4+1] cyclization of prop-2-yn-1-ones and isocyanides
《Chinese Chemical Letters》2021年第1期437-440,共4页Yingying Shan Lei Su Dianpeng Chen Min Yang Wenlin Xie Guanyinsheng Qiu 
Financial supports from the Natural Science Foundation of Shandong Province(Nos.ZR2019PB004 and ZR2018BB029);the Natural Science Foundation of China(Nos.21502069 and 21772067)are gratefully acknowledged。
A palladium-catalyzed [4+1] cycloaddition of prop-2-yn-1-ones with double isocyanides is developed herein.The transformation worked well to produce a series of 2-amino-4-cyanofurans with high efficiency and a broad re...
关键词：[4+1]Cycloaddition ISOCYANIDES Palladium catalysis FURAN PYRROLE 
Metal-free photo-induced radical C-P and C-S bond formation for the synthesis of 2-phosphoryl benzothiazoles
《Chinese Chemical Letters》2020年第5期1313-1316,共4页Wenchao Yang Bing Li Mingming Zhang Shuang Wang Yigang Ji Sa Dong Jianguo Feng Shuzhong Yuan 
financial support from the Natural Science Foundation of the Jiangsu Higher Education Institutions of China(No.19KJB150020);Basic Research Project(Natural Science Foundation for Young Scholars)of Jiangsu Province,China(No.BK20170489,BK20180916);High Level Introduction of Talent Research Start-up Foundation of YZU(No.137011457);China Postdoctoral Science Foundation(No.2019T120471)。
We reveal here a visible-light promoted phosphorylation of 2-isocyanoaryl thioethers for the first time with concomita nt C(sp3)-S bond cleavage and imidoyl C-S fo rmation.Additionally,this method features the use of ...
关键词：PHOSPHORYLATION Photo-induced ISOCYANIDES Radical cascade reaction H-Phosphorus oxides 
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