Charge transfer complex enabled photoreduction of ether phosphonium salts for the selective oxyalkylation of enamides  

作　　者：Sen Qiao Kunquan Chen Qiang Liu Zhixiang Wang Xiangyu Chen 

机构地区：[1]School of Chemical Sciences,University of the Chinese Academy of Sciences,Beijing 100049,China [2]Binzhou Institute of Technology,Weiqiao-UCAS Science and Technology Park,Binzhou 256606,China

出　　处：《Chinese Chemical Letters》2024年第2期411-414,共4页中国化学快报（英文版）

基　　金：supported by the National Natural Science Foundation of China(No.22001248);the Fundamental Research Funds for the Central Universities and University of Chinese Academy of Sciences.

摘　　要：A charge transfer complex(CTC)-enabled photoreduction of ether phosphonium salts for the generation of oxyalkyl radicals was described.The photoreduction provides a convenient method to achieve selective oxyalkylation of enamides with broad substrate scope.The method features operational simplicity,mild and inherent green conditions.

关 键 词：ENAMIDES Phosphonium salts ETHERS Charge transfer complex Visible light 

分 类 号：O644.1[理学—物理化学] O643.36[理学—化学]