ANTI-MARKOVNIKOV

作品数：10被引量：23H指数：3
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Palladium-Catalyzed anti-Markovnikov Halosulfonamidation of Unactivated Alkene
《Chinese Journal of Chemistry》2024年第5期464-470,共7页Bowen Wang Jianxiao Li Wanqing Wu Huanfeng Jiang 
Financial support was provided by the National Natural Science Foundation of China(22231002 and 21871095);the Key-Area Research and Development Program of Guangdong Province(2020B010188001).
Palladium-catalyzed regioselective amination of unactivated alkene remains a challenge and is of great interest.Herein,a three-component coupling of unactivated alkene,sulfonamide,and N-halo compounds accessing vicina...
关键词：Unactivated alkene anti-Markovnikov aminopalladation Vicinal haloamine Palladium catalysis Halosulfonamidation SELECTIVITY N-Halo compounds 
Anti-Markovnikov ring-opening of sulfonium salts with alkynes by visible light/copper catalysis被引量：1
《Science China Chemistry》2023年第3期791-798,共8页Xuan Li Min Jiang Junze Zuo Xiuyan Song Jian Lv Daoshan Yang 
supported by the National Natural Science Foundation of China(22271170);the Scientific Research Foundation of Qingdao University of Science and Technology(1203043003457).
Internal alkynes are widespread skeletons in bioactive molecules and materials which are also used as important building blocks in chemical synthesis. Herein, we report a novel and efficient copper-catalyzed Sonogashi...
关键词：radical reaction visible-light photocatalysis sulfonium salts copper catalysis ALKYNES 
Manganese-Catalyzed Anti-Markovnikov Hydroarylation of Enamides:Modular Synthesis of Arylethylamines
《Chinese Journal of Chemistry》2022年第13期1546-1552,共7页Yjie He Chaoyu Du Jian Han Jie Han Chengjian Zhu Jin Xie 
We gratefully acknowledge the National Natural Science Foundation of China(22122103,22101130,22001116,21971108,21971111,21732003);the National Key Research and Development Program of China(2021YFC2101901);the Fundamental Research Funds for the Central Universities(020514380252);the Natural Science Foundation of Jiangsu Province(Grant No.BK20190006);the Guangdong Basic and Applied Basic Research Foundation(2020A1515110816);the"Innovation&Entrepreneurship Talents Plan"of Jiangsu Province.Nian Li,Chuan-Gang Zhao,Junheng Liu are warmly acknowledged to reproduce experimental procedures for products 3ii,5p and 3a.
The arylethylamine framework is a prevalent motif in a great range of biologically important organic compounds.One intractable task for frontline drug discovery is to find structurally new medicine candidates instead ...
关键词：ALKENES ANTI-MARKOVNIKOV Homogeneous catalysis AMINES Difunctionalization 
Visible-Light-Driven Anti-Markovnikov Hydrocarboxylation of Acrylates and Styrenes with CO_(2)被引量：4
《CCS Chemistry》2021年第6期1746-1756,共11页He Huang Jian-Heng Ye Lei Zhu Chuan-Kun Ran Meng Miao Wei Wang Hanjiao Chen Wen-Jun Zhou Yu Lan Bo Yu Da-Gang Yu 
Financial support was provided by the the National Natural Science Foundation of China(nos.21822108,21822303,21801176,21772129,and 21772020);the Fok Ying Tung Education Foundation(no.161013);Sichuan Science and Technology Program(nos.2019YJ0379 and 20CXTD0112);the Fundamental Research Funds for the Central Universities.
Light-driven carbon dioxide(CO_(2))capture and utilization is one of the most fundamental reactions in Nature.Herein,we report the first visible-light-driven photocatalyst-free hydrocarboxylation of alkenes with CO_(2...
关键词：visible light carbon dioxide chargetransfer complex anti-Markovnikov selectivity CARBOXYLATION 
Photo-induced anti-Markovnikov hydroalkylation of unactivated alkenes employing a dual-component initiator被引量：1
《Chinese Chemical Letters》2021年第2期681-684,共4页Yachao Zhang Liang-Liang Mao Sifan Hu Yi Luan Huan Cong 
supported by the Strategic Priority Research Program of the Chinese Academy of Sciences (No.XDB17000000);the National Natural Science Foundation of China (Nos.21672227, 21922113);the National Key Research and Development Program of China (No.2017YFA0206903);Beijing Natural Science Foundation (No.L182020);Fundamental Research Funds for the Central Universities (No.FRF-TP-19-013B1);K.C.Wong Education Foundation,and the TIPC Director’s Fund。
Metal-free anti-Markovnikov hydroalkylation of unactivated alkenes with cyanoacetate has been developed,featuring the use of a dual-component initiator containing an organic photocatalyst and a radical precursor.When ...
关键词：PHOTOCATALYSIS ANTI-MARKOVNIKOV Alkene hydroalkylation Single-electron transfer RADICAL 
New strategy for production of primary alcohols from aliphatic olefins by tandem cross-metathesis/hydrogenation
《Chinese Chemical Letters》2020年第6期1525-1529,共5页Ruilong Jia Zhijun Zuo Xu Li Lei Liu Jinxiang Dong 
financially supported by the National Natural Science Foundation of China(Nos.21322608 and 21276174);the Natural Science Foundation of Shanxi Province(No.201801D121055);Program for the Shanxi Young Sanjin Scholar。
Primary alcohols are widely used in industry as solvents and precursors of detergents.The classic methods for hydration of terminal alkenes always produce the Markovnikov products.Herein,we reported a reliable approac...
关键词：Primary alcohols Aliphatic olefins Allyl alcohol Cross-metathesis/hydrogenation Anti-Markovnikov regioselectivity 
Iodine（Ⅲ） reagent（ABX–N3）-induced intermolecular anti-Markovnikov hydroazidation of unactivated alkenes被引量：2
《Science China Chemistry》2019年第11期1537-1541,共5页Xiaonan Li Pinhong Chen Guosheng Liu 
supported by the National Basic Research Program of China(973-2015CB856600);the National Natural Science Foundation of China(21532009,21821002,21790330,21761142010);the Science and Technology Commission of Shanghai Municipality(17XD1404500,17QA1405200,17JC1401200);the strategic Priority Research Program(XDB20000000);the Key Research Program of Frontier Science(QYZDJSSW-SLH055)of the Chinese Academy of Sciences
Anti-Markovnikov hydroazidation of unactivated alkenes using ABX–N3 as an initiator has been developed at room temperature,wherein hydrogen azide(HN3)acts as both hydrogen and azidating agent.Notably,the HN3 reagent ...
关键词：ANTI-MARKOVNIKOV hydroazidation iodine(Ⅲ) reagent(ABX–N3) unactivated alkenes 
Pt-Ni alloy catalysts for highly selective anti-Markovnikov alkene hydrosilylation被引量：3
《Science China Materials》2018年第10期1339-1344,共6页Qiang Li Shufang Ji Mufan Li Xiangfeng Duan 
supported by the National Natural Science Foundation of China (21671021);the Fundamental Research Funds for the Central Universities (2015ZCQ-LY-03)
Alkene hydrosilylation with homogeneous catalysts is an industrially important reaction for the preparation of organosilicon compounds such as silicone-based release coatings, surfactants, adhesives and molding produc...
关键词：硅氢加成反应 铂基催化剂 镍合金 烯烃 高选择性 工业化应用 英文 硅烷偶联剂 
Ring strain strategy for the control of regioselectivity. Goldcatalyzed anti-Markovnikov cycloisomerization initiated tandem reactions of alkynes被引量：1
《Science Bulletin》2017年第5期352-357,共6页Chao Shu Long Li Tong-De Tan Ding-Qiang Yuan Long-Wu Ye 
supported by the National Natural Science Foundation of China(21272191,21572186 and 21622204);the Natural Science Foundation of Fujian Province for Distinguished Young Scholars(2015J06003);the President Research Funds from Xiamen University(20720150045);NFFTBS(J1310024)
Gold-catalyzed nucleophilic addition to terminal alkynes has received considerable interest in the past decade, as this chemistry offers a highly efficient and regioselective way for CAC, CAH and CAX bond formation. H...
关键词：GOLD HETEROCYCLES Ring strain CYCLIZATION Tandem reaction 
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