Photo-induced anti-Markovnikov hydroalkylation of unactivated alkenes employing a dual-component initiator  

作　　者：Yachao Zhang Liang-Liang Mao Sifan Hu Yi Luan Huan Cong 

机构地区：[1]School of Materials Science and Engineering.University of Science and Technology Beijing,Beijing 100083,China [2]Key Laboratory of Photochemical Conversion and Optoelectronic Materials,Technical Institute of Physics and Chemistry,Chinese Academy of Sciences,Beijing 100190,China [3]School of Future Technology,University of Chinese Academy of Sciences,Beijing 100190,China

出　　处：《Chinese Chemical Letters》2021年第2期681-684,共4页中国化学快报（英文版）

基　　金：supported by the Strategic Priority Research Program of the Chinese Academy of Sciences (No.XDB17000000);the National Natural Science Foundation of China (Nos.21672227, 21922113);the National Key Research and Development Program of China (No.2017YFA0206903);Beijing Natural Science Foundation (No.L182020);Fundamental Research Funds for the Central Universities (No.FRF-TP-19-013B1);K.C.Wong Education Foundation,and the TIPC Director’s Fund。

摘　　要：Metal-free anti-Markovnikov hydroalkylation of unactivated alkenes with cyanoacetate has been developed,featuring the use of a dual-component initiator containing an organic photocatalyst and a radical precursor.When combined,the two components can undergo visible light-induced singleelectron transfer,and serve as a versatile and effective alkyl radical generator.

关 键 词：PHOTOCATALYSIS ANTI-MARKOVNIKOV Alkene hydroalkylation Single-electron transfer RADICAL 

分 类 号：O621.25[理学—有机化学]