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supported by the National Natural Science Foundation of China(Nos.21402116 and 21502111);the Key Scientific and Technological Project of Henan Province(No.222102310607);the Key Science Research of Education Committee in Henan Province(Nos.21A150044 and 22A150051);the Shandong Provincial Natural Science Foundation(Nos.ZR2023QH502 and ZR2023QB172);the Doctoral Research Foundation of Zaozhuang University.
We first describe a photoinduced decatungstate-catalyzed direct coupling of cycloalkanes and cyclic aldimines.The desired products were generated in moderate to good yields with wide substrate scope under mild reactio...
supported by the National Key R&D Program of China(2022YFB4201802);the Xuzhou Basic Research Project(KC23018);the Fundamental Research Funds for the Central Universities(2023-00104);the Priority Academic Program Development of Jiangsu Higher Education Institutions。
Developing an energy supply-chain based on renewable biomass holds great potential to build a low carbon society.High-energy-density(HED)jet fuel,featuring unique fused/strained cycloalkanes,is of great significance f...
This article elaborates on the research achievements of domestic and foreign researchers in exploring the conversion pathways and reaction mechanisms of cyclohexane catalytic cracking in recent years.It analyzes the e...
funded by grants from the National Natural Science Foundation of China(No.52236010,51876210);the Fundamental Research Funds for the Central Universities(No.2242022R10058)。
In this work,a“cyclopentanone-vanillin”strategy was proposed for the preparation of jet fuel range cycloalkanes from lignocellulose-derived ketones and lignin-derived aldehydes via aldol condensation and hydrodeoxyg...
funding from the National Natural Science Foundation of China(grant nos.22071209,22071206);the National Youth Talent Support Program,the Natural Science Foundation of Fujian Province of China(grant no.2017J06006);the Fundamental Research Funds for the Central Universities(grant no.20720190048).
The direct conversion of unactivated alkanes and cycloalkanes into structurally diverse molecules through aliphatic C—H functionalization is a useful process, which has attracted intense interest from academia and in...
The development of practical methods for the direct and selective C(sp^(3))‒H functionalization of hydrocarbons is an attractive topic in synthetic chemistry.Although the radical‐mediated hydrogen atom transfer(HAT)p...
This work was supported by the Strategic Priority Research Program of the Chinese Academy of Sciences(XDB36000000);the National Natural Science Foundation of China(21590811,21777167,21827809);and the National Key R&D Program of China(2018YFA0209302).
Bothβ-andγ-hydroxyketone structures are important units in biologically active molecules,synthetic drugs and fine chemicals.Although there are some routes available for their manufacture from pre-functionalized grou...
A combinatorial method based on the determination of the averaged weight of permutations controlling the chirality/achirality fittingness of 2n substitution sites of the monocyclic cycloalkane allows to obtain general...
Supported by the National Natural Science Foundation of China(Grant No.21476270,21306176,21776259,21276006);Scientific Research Launching Foundation of Zhejiang University of Technology(Grant No.G2817101103)
Autoxidation of cycloalkanes (C5-C8) with molecular oxygen under catalyst-free and solvent-free conditions was conducted systematically for the first time, focusing on the autoxidation temperature and product distri...
supported by the National High Technology Research and Development Program of China(2009AA044701);the Program for Zhejiang Leading Team of S&T Innovation(2013TD07)
To get deep understanding of the reaction mechanism of coal pyrolysis in hydrogen plasma, the decomposition reaction pathways of aliphatic hydrocarbons and cycloalkanes, which are two main components in volatiles from...