Photoinduced decatungstate-catalyzed direct coupling of cycloalkanes and cyclic aldimines  

作　　者：Jingjing Wang Feng Li Kai Liu Chong Li Sheng Cao Yuxiang Wu Yongjun Yuan Fei Teng Teng Wang Yao Zhou 

机构地区：[1]College of Food Science and Pharmaceutical Engineering,Zaozhuang University,Zaozhuang,Shandong 277160,China [2]School of Chemistry,Beihang University,Beijing 100191,China [3]College of Chemistry and Chemical Engineering,Hubei Normal University,Huangshi,Hubei 435002,China [4]Nantong Jinghua Pharmaceutical Co.,Ltd,Nantong,Jiangsu 226005,China

出　　处：《Green Synthesis and Catalysis》2024年第4期315-318,共4页绿色合成与催化（英文）

基　　金：supported by the National Natural Science Foundation of China(Nos.21402116 and 21502111);the Key Scientific and Technological Project of Henan Province(No.222102310607);the Key Science Research of Education Committee in Henan Province(Nos.21A150044 and 22A150051);the Shandong Provincial Natural Science Foundation(Nos.ZR2023QH502 and ZR2023QB172);the Doctoral Research Foundation of Zaozhuang University.

摘　　要：We first describe a photoinduced decatungstate-catalyzed direct coupling of cycloalkanes and cyclic aldimines.The desired products were generated in moderate to good yields with wide substrate scope under mild reaction conditions.The mechanistic study revealed a radical process.In addition,the usefulness of the reaction in organic synthesis was proved by the scale-up synthesis as well as the late-stage modification of drug-like molecules.

关 键 词：PHOTOINDUCED DECATUNGSTATE C-H functionalization CYCLOALKANES Cyclic aldimines 

分 类 号：O62[理学—有机化学]