Sustainable production of high-energy-density jet fuel via cycloaddition reactions  

作　　者：Yan-Cheng Hu Yingying Zhao Ning Li Jing-Pei Cao 

机构地区：[1]School of Chemical Engineering and Technology,China University of Mining and Technology,Xuzhou 221116,Jiangsu,China [2]School of Education Science,Jiangsu Normal University,Xuzhou 221116,Jiangsu,China [3]CAS Key Laboratory of Science and Technology on Applied Catalysis,Dalian Institute of Chemical Physics,Chinese Academy of Sciences,Dalian 116023,Liaoning,China

出　　处：《Journal of Energy Chemistry》2024年第8期712-722,I0016,共12页能源化学（英文版）

基　　金：supported by the National Key R&D Program of China(2022YFB4201802);the Xuzhou Basic Research Project(KC23018);the Fundamental Research Funds for the Central Universities(2023-00104);the Priority Academic Program Development of Jiangsu Higher Education Institutions。

摘　　要：Developing an energy supply-chain based on renewable biomass holds great potential to build a low carbon society.High-energy-density(HED)jet fuel,featuring unique fused/strained cycloalkanes,is of great significance for volume-limited military aircrafts,as their high density and combustion heat can extend flight duration and increase the payload.Therefore,the exploration of biomass-based routes towards HED fuel has drawn much attention over the past decade.Cycloaddition reaction features rapid construction of various carbocycles in an atom-and step-economical fashion.This elegant strategy has been widely applied in the manufacture of sustainable HED fuel.Here we carefully summarize the progress achieved in this fascinating area and the review is categorized by the cycloaddition patterns including[4+2],[2+2],[4+4],and[2+1]cycloadditions.Besides,the energy densities of the as-prepared biofuels and petroleumbased fuels(conventional Jet-A and advanced JP-10)are also compared.This review will provide important insights into rational design of new HED fuel with different ring-types/sizes and inspire the chemists to turn those literature studies into practical applications in military field.

关 键 词：High-energy-density fuel Biomass-based chemicals CYCLOADDITION CYCLOALKANES CATALYSIS 

分 类 号：TQ517[化学工程]