制备工艺对氮化硅泡沫陶瓷中晶须生长的影响  

Effect of Fabrication Process on Whisker Growth in Si_3N_4 Foam Ceramics

作　　者：李和欣[1] 余娟丽[1] 张笑妍[1] 杨金龙[1] 黄勇[1] 

机构地区：[1]清华大学材料科学与工程系,新型陶瓷与精细工艺国家重点实验室,北京100084

出　　处：《硅酸盐学报》2012年第9期1294-1299,共6页Journal of The Chinese Ceramic Society

基　　金：国家自然科学基金(51172120);国家创新方法工作专项(2011IM030800);北京市科技计划(Z101103055010003)资助项目

摘　　要：采用直接起泡法,通过氮化硅颗粒稳定泡沫机制制备氮化硅泡沫陶瓷,研究了烧结温度、保温时间、烧结氮气压、烧结助剂(Al2O3+Y2O3)添加量以及Al2O3与Y2O3质量比对氮化硅泡沫陶瓷中晶须生长的影响,分析了泡沫陶瓷的微观结构。结果表明:通过工艺条件的控制可得到由长柱状β-Si3N4晶粒构成的显微结构;当烧结温度为1750℃、保温时间为4 h、烧结气压为0.9 MPa、烧结助剂添加量为6%(质量分数)、Al2O3与Y2O3质量比为1:1时,β-Si3N4晶粒的长径比达到12以上。Si3N4 foam ceramics were prepared by a direct foaming method based on the particle-stabilized foam mechanism. The influences of sintering temperature, holding time, sintering gas pressure, addition amount of sintering additive（Al2O3＋Y2O3） and m（Al2O3）：m（Y2O3） on the whisker growth in Si3N4 foam ceramics were investigated. The microstructure of the sintered Si3N4 foam ceramics was also analyzed. The results show that the Si3N4 foam ceramics with an elongated rod-shaped β-Si3N4 microstructure are obtained via the control of the processes. The ratio of grain length to diameter of the elongated rod-shaped β-Si3N4 grains was greater than 12 when Si3N4 foam ceramics were sintered at the sintering additive of 6% （in mass）, m（Al2O3）：m（Y2O3） of 1：1, a nitrogen pres- sure of 0.9MPa and 1 750 ℃ for 4h.

关 键 词：氮化硅 泡沫陶瓷 烧结助剂 晶须 颗粒稳定泡沫 

分 类 号：TQ174[化学工程—陶瓷工业]