吴淞口近岸湿地沉积物中腐殖质的组成特征  

Composition Characteristics of Humic Substances in Wusong Estuary Coastal Wetland Sediment

作　　者：钟成林[1] 刘晓艳[1] 张新颖[1] 曹正楠[1] 刘发辉[1] 刘珊珊[1] 陈丽莎[1] 胡艳[1] 

机构地区：[1]上海大学环境与化学工程学院,上海200444

出　　处：《上海大学学报（自然科学版）》2012年第4期408-412,共5页Journal of Shanghai University:Natural Science Edition

基　　金：国家自然科学基金资助项目(41073072);上海市重点学科建设资助项目(S30109)

摘　　要：土壤腐殖质会对土壤中污染物的迁移和转化产生重要影响.根据Pallo法分组,对吴淞口近岸湿地沉积物中腐殖质所含的富里酸(fulvic acid,FA)、胡敏酸(humic acid,HA)和胡敏素(humin,HM)3种组分进行分离,并分析FA,HA和HM的色调系数(Δlog K)、红外光谱以及元素组成特征.结果表明,吴淞口近岸湿地沉积物中腐殖质的质量比为3.20 g/kg,FA和HM组分分别占腐殖质总质量的40%和55%.FA的Δlog K值较HA高,且其分子结构简单,演化程度和芳构化程度低.FA的主要官能团有—CH2,—CH3,—COOH和C==O等,HA的主要官能团有—CH2,—CH3,—COOH和芳基上的C==C等.吴淞口近岸湿地沉积物中的腐殖质的芳构化和腐殖化程度低,其所含各组分的芳构化程度为FA<HA<HM.Humic substances have important influences on dissipation of pollutants in soil. According to Pallo classification method, the three fractions of fulvic acid （FA） , humic acid （HA） and humin （HM） were separated from the sediment in the Wusong estuary coastal wetland. The optical property Alog K, infrared spectra and elemental composition of the humic fractions were analyzed. The results indicated that the content of humic substances in the Wusong estuary coastal wetland was 3.20 g/kg, and FA and HM were 40% and 55% of the total humic substances, respectively. Moreover, the Alog K value of FA was higher than HA＇ s, showing that the degree of evolution and aromatization of FA was low. The main functional groups of FA and HA were --CH2, --CH3, --COOH, C=0 and --CH2, --CH3, --COOH, C = C, respectively. Humic substances in the Wusong estuary coastal wetland belonged to low degree of humification and aromatization. The aromatization degree of humic substances was gradually enhanced by FA 〈 HA 〈 HM.

关 键 词：吴淞口 湿地 沉积物 腐殖质 

分 类 号：X131.3[环境科学与工程—环境科学] S153.6[农业科学—土壤学]