负载的Ni催化剂上植物油脂加氢脱氧制备第二代生物柴油  

Catalytic hydrodeoxygenation of vegetable oil over Ni catalysts to produce second-generation biodiesel

作　　者：左华亮[1,2] 刘琪英[1] 王铁军[1] 史娜[1] 刘建国[1,2] 马隆龙[1] 

机构地区：[1]中国科学院广州能源研究所可再生能源与天然气水合物重点实验室,广东广州510640 [2]中国科学院研究生院,北京100049

出　　处：《燃料化学学报》2012年第9期1067-1073,共7页Journal of Fuel Chemistry and Technology

基　　金：国基NSFC/JST重大国际合作项目(51161140331);国家重点基础研究发展规划(973计划;2012CB215304)

摘　　要：在半连续反应器中,以棕榈酸甲酯为植物油脂模型化合物,进行了加氢脱氧制取高品质生物柴油燃料的研究。采用浸渍法制备了HY、SiO2、γ-Al2O3及SAPO-11四种载体负载的Ni催化剂,采用XRD、NH3-TPD、H2-TPR、BET、SEM等技术进行催化剂表征。结果表明,Ni/SAPO-11催化剂由于SAPO-11表面呈现的弱酸和中强酸性质,在保持较高的加氢脱氧反应性的同时,抑制了裂解反应的发生,具有较好的催化性能。进一步对SAPO-11上不同的Ni负载量、反应温度、反应压力等进行了研究,发现当Ni负载量为7%,反应温度为220℃,压力为2MPa时,催化剂具有较高的催化性能,棕榈酸甲酯的转化率达到了99.8%,C9～16烷烃的总选择性为92.71%。A series of Ni catalysts supported on HY,SiO2,γ-Al2O3 and SAPO-11 were prepared by incipient-wetness impregnation and characterized by XRD,NH3-TPD,H2-TPR,BET and SEM techniques.Their catalytic performance in hydrodeoxygenation（HDO） of vegetable oil to produce the second-generation biodiesel was evaluated in a semi-batch reactor by using methyl palmitate as a model compound.Owning to the weak and medium acidic properties of SAPO-11,the Ni/SAPO-11 catalyst exhibits high activity in the HDO of methyl palmitate and capability of inhibiting the feedstock and long-chain alkanes from being cracked.The effect of Ni loading,reaction temperature and pressure on the HDO behavior over Ni/SAPO-11 catalyst was considered.Under 220 ℃ and 2 MPa,Ni/SAPO-11 catalyst with a Ni loading of 7% performs best in HDO;the conversion of methyl palmitate and the selectivity towards C9~16 alkanes reach 99.8% and 92.71%,respectively.

关 键 词：植物油脂 棕榈酸甲酯 加氢脱氧 NI基催化剂 第二代生物柴油 

分 类 号：TQ645.1[化学工程—精细化工]