1,2,3,4-四嗪-1,3-二氧化物含能材料的研究进展  

Progress in the Energetic Materials Based on 1,2,3,4-Tetrazine 1,3-Dioxide

作　　者：毕福强[1] 王伯周[1] 李翔志[1] 樊学忠[1] 许诚[1] 葛忠学[1] 

机构地区：[1]西安近代化学研究所,陕西西安710065

出　　处：《含能材料》2012年第5期630-637,共8页Chinese Journal of Energetic Materials

基　　金：国防基础科研计划项目(B0920110051)

摘　　要：1,2,3,4-四嗪-1,3-二氧化物是构建高能量密度材料的含能结构单元。重点介绍了关键中间体邻氨基叔丁基氧化偶氮化合物的两种合成方法以及环化合成1,2,3,4-四嗪-1,3-二氧化物的技术途径,系统综述了苯并1,2,3,4-四嗪-1,3-二氧化物衍生物、吡啶并1,2,3,4-四嗪-1,3-二氧化物衍生物、单环1,2,3,4-四嗪-1,3-二氧化物的合成方法;重点介绍了典型含能化合物呋咱并[3,4-e]-1,2,3,4-四嗪-4,6-二氧化物(FTDO)及1,2,3,4-四嗪并[5,6-e]-1,2,3,4-四嗪-1,3,5,7-四氧化物(TTTO)的研究进展。1,2,3,4-Tetrazine 1,3-dioxide is a potential energetic moiety in the design and synthesis of high energy density materials. The synthetic methods of 1,2,3,4-tetrazine 1,3-dioxide and its key intermediate 2-tert-butyldiazene oxide were reviewed respectively, and the research progresses in benzo-1,2,3,4-tetrazine 1,3-dioxide, pyrido-1,2,3,4-tetrazine 1,3-dioxide, nonannulated 1,2,3,4-tetrazine 1,3-dioxides and their derivatives were reviewed in detail. Moreover, the development progress of furazano[3,4-e]-1,2,3,4-tetrazine 4,6-dioxide （FTDO） and 1,2,3,4-tetrazino[5,6-e]-1,2,3,4-tetrazine 1,3,5,7-tetraoxide（TTTO）, two typically energetic materials, was presented.

关 键 词：有机化学 1 2 3 4-四嗪-1 3-二氧化物 研究进展 

分 类 号：TQ560.1[化学工程—炸药化工]