连苯三酚缩二乙烯基苯树脂活性醚化物的合成与成像应用  

SYNTHESIS AND IMAGING APPLICATIONS OF THE ACTIVE ETHER COMPOUNDS OF PYROGALLOL POLYCONDENSATION DIVINYLBENZENE RESIN

作　　者：沙栩正[1] 庞玉莲[1] 邹应全[1] 

机构地区：[1]北京师范大学化学学院,北京100875

出　　处：《高分子学报》2012年第12期1448-1458,共11页Acta Polymerica Sinica

摘　　要：通过乙烯基乙醚和连苯三酚缩二乙烯基苯树脂(PDVB resin)的羟基加成,合成了具有缩醛结构的活性醚化物,并对该活性醚化物的合成条件进行优化.这种具有缩醛结构的活性醚化物具有常温酸解和热解性能,作为阻溶促溶剂可用于常温化学增幅阳图感光成像和阳图热敏成像中.用于阳图热敏CTP感热成像配方中,使得版材具有高感度、高抗碱性、高稳定性;用于阳图CTcP感光成像配方中,使得该版材的综合成像性能优良;用于正性光致抗蚀剂成像配方中,使得该正性光致抗蚀剂具有高感度和高分辨率。A kind of active ether compound with acetal structure was synthesized through the adding-reaction between ethyl vinyl ether and pyrogallol polycondensation resins.The optimized reaction conditions are as follows：35℃,the mixture of methylene chloride and acetone（50∶50） as the solvent,sulfamic acid as the catalyst,the molar ratio of vinyl ether to phenolic hydroxyl group being 3∶1,reacting for 14 h.This kind of active ether compound can be used in room temperature chemically amplified positive photosensitive imaging and positive thermal imaging as an inhibitational/accelerational reagent for being able to be acid-decomposed and heat-decomposed under room temperature.Being used in CTP thermal imaging directions,it makes for the plates＇ high sensitivity,anti-alkaline and high stability.Being used in positive CTcP photosensitive imaging directions,it makes for the plates＇ excellent performance of integrated imaging.Being used in positive photoresist imaging directions,it makes for the positive photoresist high sensitivity and high resolution.

关 键 词：活性醚化物 阻溶促溶剂 阳图热敏CTP版 阳图CTcP版 正性抗蚀剂 

分 类 号：TS804[轻工技术与工程]