呋咱并[3,4-e]-1,2,3,4-四嗪-1,3-二氧化物(FTDO)的合成  

Synthesis of Furazano-1,2,3,4-tetrazine-1,3-dioxide

作　　者：董琳琳[1] 张光全[2] 池钰[2] 范桂娟[2] 何玲[1] 陶国宏[1] 黄明[2] 

机构地区：[1]四川大学化学学院,四川成都610064 [2]中国工程物理研究院化工材料研究所,四川绵阳621900

出　　处：《含能材料》2012年第6期690-692,共3页Chinese Journal of Energetic Materials

基　　金：国家自然科学基金(21103116)

摘　　要：以乙二醛和盐酸羟胺为原料,合成了二氨基乙二肟(DAG),经过脱水成环得到3,4-二氨基呋咱(DAF),再在30%的双氧水作用下氧化得到亚硝基氨基呋咱(ANF),ANF与N,N-二溴叔丁基胺缩合得到3-氨基-4-(叔丁基氧化偶氮基)呋咱,最后经四氟硼酸銷(NO2BF4)硝化成环得目标产物FTDO,总收率18%(基于DAF),并对其进行了红外和核磁表征。Furazano[3,4-e]-1,2,3,4-tetrazine-1 ,3-dioxide（FTDO） has been synthesized in the work. Firstly, diaminoglyoxime （DAG） was obtained via the one-step reaction of glyoxal with hydroxylammonium chloride. 3,4-Diaminofurazan（DAF） was obtained by the dehydration reaction of DAG. Then the oxidation of DAF using 30% H2O2 gave 3-amino-4-nitrosofurazan（ANF） , and 3-amino-4-（tert-butyl）azoxyfurazan was prepared after the treatment of ANF with tert-butyI-N,N-dibromide in dichloromethane. Finally, FTDO was obtained by the nitration and cyclization of 3-amino-4-（tert-butyl）azoxyfurazan with nitronium tetraflu-orobrate （ NO,BF4 ） in acetonitrile with the total yield of 18%,. The structures of FTDO and its intermediates were characterized by IR and NMR.

关 键 词：有机化学 呋咱并[3 4-e]-1 2 3 4-四嗪-1 3-二氧化物(FTDO) 含能化合物 合成 

分 类 号：TQ560.1[化学工程—炸药化工]