Formation of silacycles via metal-mediated or catalyzed Si-C bond cleavage  

作　　者：WANG LiLi DUAN Zheng 

机构地区：[1]College of Chemistry and Molecular Engineering,Zhengzhou University

出　　处：《Chinese Science Bulletin》2013年第3期307-315,共9页

基　　金：supported by the National Natural Science Foundation of China (21072179)

摘　　要：Silacycles play a very important role in modern organic chemistry and materials science.Construction of silacyclic skeletons via metal-mediated or catalyzed Si-C bond cleavage has attracted much recent attention.Several interesting and useful synthetic strategies have been reported in the literature.In this review,we have summarized recent developments on metal-mediated or catalyzed Si-C bond cleavage,which lead to the synthesis of silacycles,including silacyclobutenes,silacyclopentanes,silacyclopentadienes(siloles),6-membered silacycles,and their derivatives.Silacycles play a very important role in modem organic chemistry and materials science. Construction of silacyclic skeletons via metal-mediated or catalyzed Si-C bond cleavage has attracted much recent attention. Several interesting and useful synthetic strategies have been reported in the literature. In this review, we have summarized recent developments on metal-mediated or catalyzed Si-C bond cleavage, which lead to the synthesis of silacycles, including silacyclobutenes, silacyclopentanes, silacyclopentadienes （siloles）, 6-membered silacycles, and their derivatives.

关 键 词：键断裂 介导 金属 材料科学 有机化学 衍生物 催化 合成 

分 类 号：O643.32[理学—物理化学]