双氯芬酸在水环境中光降解的初步研究  

Photodegration mechanism of diclofenac in aqueous environment

作　　者：张楠[1,3] 刘国光[1,2] 刘海津[1] 汪英灵[1] 李通[1] 

机构地区：[1]河南师范大学化学与环境科学学院,黄淮水污染与控制省部共建教育部重点实验室,新乡453007 [2]广东工业大学环境科学与工程学院,广州510006 [3]河南科技学院资源与环境学院,新乡453003

出　　处：《环境化学》2013年第1期42-47,共6页Environmental Chemistry

基　　金：广东省-教育部省部产学研项目(2009B090300342);国家水体污染控制与治理科技重大专项(2009ZX07211-005-03)资助

摘　　要：考察了在模拟太阳光照射下,双氯芬酸初始浓度、pH值、光强、温度、丙酮和双氧水对双氯芬酸光解的影响,并通过淬灭实验初步探讨了双氯芬酸光解.结果表明,双氯芬酸的光降解过程符合准一级动力学方程.光解速率随着双氯芬酸初始浓度的降低、光强的增强以及温度的升高而增大.当pH值从3变化到5时,反应速率常数变大;pH值从5变到8时,反应速率常数变小,再继续增大pH值,反应速率常数增大.水环境中存在的双氧水和丙酮对双氯芬酸的光解具有促进作用.最后,通过淬灭实验表明双氯芬酸的光解过程包括直接光解以及通过活性氧物种进行的自敏化光解.The effect of aquatic environmental factors on the photodegradation of diclofenac under simulated s was studied in this paper. The results demonstrate that degradation pathways proceed via pseudo first-order kinetics in all cases. temperature. The rate The pho constant todegradation rate was found to increase with increasing light intensity and gradually increased when the pH increased from 3 to 5, decreased as the pH increased from 5 to 8, and finally increased when the pH increased further from 8 to 12. H2 02 promoted the photodegradation of diclofenac due to the formation of hydroxyl radicals, and triplet state photosensitizer acetone promoted the photodegradation of diclofenac due to 3DCF＊. diclofenac underwent direct photolysis and selfsensitized photodegradati Scavenging experiments indicated that on via reactive oxygen species.

关 键 词：双氯芬酸 模拟太阳光 光解机理 自敏化光解 

分 类 号：X13[环境科学与工程—环境科学] O643.32[理学—物理化学]