Thiol-yne click polymerization  被引量:4

Thiol-yne click polymerization

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作  者:YAO BiCheng SUN JingZhi QIN AnJun TANG Ben Zhong 

机构地区:[1]MOE Key Laboratory of Macromolecular Synthesis and Functionalization,Department of Polymer Science and Engineering,Zhejiang University [2]Department of Chemistry,Institute for Advanced Study,Institute of Molecular Functional Materials,The Hong Kong University of Science & Technology

出  处:《Chinese Science Bulletin》2013年第22期2711-2718,共8页

基  金:supported by the National Natural Science Foundation of China(21222402,21174120);the National Basic Research Program of China(2009CB623605,2013CB834702);the Research Grants Council of Hong Kong(603509,HKUST2/CRF/10,604711,N_HKUST620/11)

摘  要:The research on using thiol-ene click reaction to synthesize sulfur-containing polymers with topological structures and advanced functional properties is a hot topic. However, the application of the thiol-yne reaction in the functional polymer preparation is limited and the thiol-yne click polymerization is to be further developed. In this review, we summarized recent research efforts on using thiol-yne click polymerization to synthesize polymers with topological structures. The sulfur-containing polymers were facilely prepared by photo-and thermo-initiated, amine-mediated, and transition-metal-catalyzed thiol-yne click polymerizations. These polymers are promising to be used as drug-delivery vehicles, high refractive index optical materials, photovoltaic materials, and biomaterials etc.The research on using thiol-ene click reaction to synthesize sulfur-containing polymers with topological structures and advanced functional properties is a hot topic. However, the application of the thiol-yne reaction in the functional polymer preparation is limited and the thiol-yne click polymerization is to be further developed. In this review, we summarized recent research efforts on using thiol-yne click polymerization to synthesize polymers with topological structures. The sulfur-containing polymers were facilely prepared by photo- and thermo-initiated, amine-mediated, and transition-metal-catalyzed thiol-yne click polymerizations. These polymers are promising to be used as drug-delivery vehicles, high refractive index optical materials, photovoltaic materials, and biomaterials etc.

关 键 词:含硫聚合物 巯基 过渡金属催化 拓扑结构 反应合成 合成聚合物 功能特性 应用程序 

分 类 号:O631.5[理学—高分子化学]

 

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