锑铁复合固体超强酸S_2O_8^(2-)/Sb_2O_3/Fe_2O_3催化合成环己酮乙二醇缩酮研究  

A Study on Catalytic Synthesis of Cyclohexanone Glycol Ketal with Antimony-Iron Compound Solid Superacids S2O82-/Sb2O3/Fe2O3

作　　者：谢晓林[1] 舒华[2] 胡梅雨[2] 吴思展[2] 

机构地区：[1]贵阳学院食品与制药工程学院,贵州贵阳550000 [2]铜仁学院生物科学与化学系,贵州铜仁554300

出　　处：《铜仁学院学报》2013年第4期115-119,共5页Journal of Tongren University

基　　金：贵州省科学技术基金项目([2010]2128);贵州省铜仁市科技计划项目(2012)63号-1成果

摘　　要：以环己酮、乙二醇为原料,自制的锑铁复合固体超强酸22 8 2 3 2 3S O/Sb O/Fe O作催化剂,合成了环己酮乙二醇缩酮。通过分析环己酮与乙二醇的摩尔比、催化剂的量、反应时间和带水剂的用量对环己酮乙二醇缩酮的产率的单因素影响,选出合成环己酮乙二醇缩酮的单因素最优方案。同时,以环己酮与乙二醇的摩尔比、催化剂的量、带水剂的用量和反应时间为因素,设计了L9(34)正交表进行实验,得出的正交试验最佳方案为A2B1C2D2,即环己酮与乙二醇的摩尔比为1.0:1.7,催化剂的量为1.0g,带水剂用量为8mL,反应时间为1.5h。在该方案下,环己酮乙二醇缩酮的产率可以达到83.69%。The cyclohexanone ethylene ketal was synthesized by cyclohexanone and glycol as starting material with homemade antimony-iron compound S2O82-/Sb2O3/Fe2O3 solid super-acid as catalyst.By analyzing single factors of the mole ratio of cyclohexanone and glycol,the catalyst amount,the reaction time and the dosage of water-carrying agent on the yield of cyclohexanone glycol ketal,the single factor optimization scheme of the synthesis of cyclohexanone glycol ketal was chosen.At the same time,taking the molar ratio of cyclohexanone and glycol,the amount of catalyst and reaction time as factors,the L9（34） orthogonal designed experiment was done to obtain the best solutions for A2B1C2D2,namely,the mole ratio of cyclohexanone and glycol for 1.0：1.7,the quality of the catalyst for 1.0 g,the reaction time for 1.5 h,and the dosage of water for 8 ml.Finally,the finding was that the yield of cyclohexanone glycol ketal could come to 83.66%.

关 键 词：固体超强酸 环己酮乙二醇缩酮 催化合成 

分 类 号：TS201.2[轻工技术与工程—食品科学] O643[轻工技术与工程—食品科学与工程]