缩乙二醇双羟基新型键合固定相的合成及性能研究  

Preparation and Properties of a Novel Dihydroxy Bonded Stationary Phase Triethylene Glycol Silica Gel

作　　者：刘武平[1] 达世禄[1] 

机构地区：[1]武汉大学化学系,武汉430072

出　　处：《高等学校化学学报》1991年第7期976-978,共3页Chemical Journal of Chinese Universities

摘　　要：双羟基硅胶键合固定相由于具有结构稳定、耐高压和抗溶剂性能强等特点,已引起色谱分析工作者的广泛注意,Regnier等曾合成含有6个碳原子的双羟基极性键合固定相,但由于碳链太短,限制了它在极性有机化合物上的应用,本文合成的新型缩乙二醇双羟基极性键合固定相(DHGBSP)表面键合浓度高(a=394 μmol/g硅胶)、热和溶剂稳定性能好。A new silica gel bonded phase, dihydroxy triethylene glycol bonded stationary phase (DHG-BSP), was synthesized. The conditions for preparation, together with its physicochemical properties and applications were studied. It is shown that the DHGBSP is an excellent material with high concentration of bonded phase(394 μmol/g), good thermal and chemical stabilities and highly selective separation for aromatic amines and some amino acids.

关 键 词：DHGBSP 芳香胺 氨基酸 分离选择性 

分 类 号：O657.7[理学—分析化学]