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作 者:王祝[1,2] 李明礼[1,2,3] 邵蓓[1,2] 邬国栋[1,2]
机构地区:[1]西藏自治区地质矿产勘查开发局中心实验室,西藏拉萨850033 [2]国土资源部拉萨矿产资源监督检测中心,西藏拉萨850033 [3]成都理工大学地球科学学院,四川成都610059
出 处:《盐业与化工》2013年第12期13-16,20,共5页Jounral of Salt and Chemical Industry
摘 要:以西藏鄂雅错湖表卤水为研究对象,依据Na+、K+、Mg2+∥SO2-4、Cl--H2O五元水盐体系25℃介稳相图,研究了卤水在25℃等温蒸发过程中的盐类结晶路线及其析出规律。实验结果表明:卤水蒸发析盐顺序依次为氯化钠、钾石盐、光卤石、泻利盐、水氯镁石和锂盐,硼酸盐在蒸发过程中不以固体形式析出,赋存于老卤中,实验结果与介稳相图基本吻合,研究结果可为盐湖的综合利用提供参考。Abstract: This paper which took the surface brines of Eyacuo Salt Lake as its research object studied the crystallization paths and precipitation regular patterns of salts in the process of 25 ℃ - isothermal evaporation of brines by referring to the metastable phase diagram of Na+ , K+ , Mg2+ // SO4 2- ,Cl4 - - H2O quinary system at 25 ℃. It was found that the crystallized path of the salt lake brine was that: halite, sylvite, carnallite, epsom salt, bischofite and lithium salt while borate was not crystallized out but concentrated in the mother solution. It showed that the 25 ℃ - isothermal e- vaporated crystallization path agreed well with the theoretical crystallized path based on the metasta- ble phase diagrams. The experiment and study provide the reference for the comprehensive utiliza- tion of hines of Eyaeuo Salt Lake.
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