配合物Nd_2(C_4H_2O_4)·(C_(10)H_2O_8)_(1.5)·2H_2O的合成及其光电性能的研究  

Study on Synthesis of Complex Nd_2(C_4H_2O_4)_2·(C_(10)H_2O_8)_(1.5)·2H_2O and Its Optical and Electrochemical Properties

作　　者：田瑶[1] 徐娟[1] 蔡李鹏[1] 曾敏[1] 范玉桥 王娟[1] 

机构地区：[1]有机化工新材料湖北省协同创新中心 湖北大学化学化工学院,湖北武汉430062

出　　处：《化学与生物工程》2014年第3期21-23,共3页Chemistry & Bioengineering

基　　金：湖北省自然科学基金资助项目(2012FFB00205);全国大学生创新训练项目(201210512054)

摘　　要：采用水热法合成了顺丁烯二酸和均苯四甲酸二酐与稀土钕的配合物.通过元素分析、红外光谱、紫外光谱、荧光光谱、循环伏安、熟重分析等对其进行了表征.室温下的荧光光谱表明,配合物在453.0 nm处具有很强的发射峰.电化学性质研究表明,配合物在-0.15～0.15 V（vs.SCE）电位范围内具有明显的电化学活性.A novel neodymium（Ⅲ） complex was synthesized with cis-butenedioic acid and pyromellitic dianhydride as ligand,and was characterized by elemental analysis,IR,UV,fluorescence spectrum analysis,cyclic voltammetry analysis and thermal gravimetric analysis.The fluorescence spectrum of the complex at room temperature showed that the complex had strong emission peak at 453.0 nm.The electrochemical properties of the complex was characterized and the result showed that the complex in the potential range of-0.15～0.15V（vs.SCE） had obvious electrochemical activity.

关 键 词：钕配合物 顺丁烯二酸 均苯四甲酸二酐 荧光 电化学性质 

分 类 号：O614.33[理学—无机化学]