Synthesis, Crystal Structure and Copper Complex of 1,3-Alternate p-tert-Butylthiacalix[4]arene 2-picolyl Schiff Base  

作　　者：HUANG Kun LIU Kai YAN Chaoguo 

机构地区：[1]College of Chemistry & Chemical Engineering, Yangzhou University, Yangzhou 225002, P.R.China

出　　处：《Chemical Research in Chinese Universities》2014年第2期245-249,共5页高等学校化学研究（英文版）

基　　金：Supported by the National Natural Science Foundation of China（No.20972132） and the Priority Academic Program Development of Jiangsu Higher Education Institutions of China.

摘　　要：A p-tert-butylthiacalix[4]arene-based polydentated ligand with four Schiff base units on 1,3-alternate position at lower rim has been prepared in three steps,which coordinated to copper ion to form a novel dicopper complex.The structures of the polydentated thiacalixarene ligand and copper complex were fully characterized by spectroscopy and X-ray single crystal diffraction method.A p-tert-butylthiacalix[4]arene-based polydentated ligand with four Schiff base units on 1,3-alternate position at lower rim has been prepared in three steps,which coordinated to copper ion to form a novel dicopper complex.The structures of the polydentated thiacalixarene ligand and copper complex were fully characterized by spectroscopy and X-ray single crystal diffraction method.

关 键 词：CALIXARENE Thiacalixarene Schiff base PYRIDINE Copper complex Crystal structure 

分 类 号：O625.312[理学—有机化学] O614.121[理学—化学]