用活性炭及部分热解碳材料进行的质子催化(英文)  

Proton catalysis with active carbons and partially pyrolyzed carbonaceous materials

作　　者：V.V.Strelko S.S.Stavitskaya Yu.I.Gorlov 

机构地区：[1]Institute for Sorption and Problems of Endoecology of ,NAS of Ukraine, 13 General Naumov St.03164, Kyiv, Ukraine

出　　处：《催化学报》2014年第6期815-823,共9页

摘　　要：The development of environmentally friendly solid acid catalysts is a priority task. Highly oxidized activated carbon and their ion-substituted (saline) forms are effective proton transfer catalysts in esterification, hydrolysis, and dehydration, and thus are promising candidates as solid acid cata-lysts. Computations by the ab initio method indicated the cause for the enchanced acidity of the carboxylic groups attached to the surface of highly oxidized carbon. The synthesis of phosphorilated carbon was considered, and the proton transfer reactions catalyzed by them in recent studies were analyzed. The development of an amorphous carbon acid catalyst comprising polycyclic carbonaceous (graphene) sheets with –SO3H, –COOH and phenolic type OH-groups was carried out. These new catalysts were synthesized by partial pyrolysis and subsequent sulfonation of carbohydrates, polymers, and other organic compounds. Their high catalytic activities in proton transfere reactions including the processing of bio-based raw materials was demonsrated.The development of environmentally friendly solid acid catalysts is a priority task. Highly oxidized activated carbon and their ion-substituted （saline） forms are effective proton transfer catalysts in esterification, hydrolysis, and dehydration, and thus are promising candidates as solid acid cata-lysts. Computations by the ab initio method indicated the cause for the enchanced acidity of the carboxylic groups attached to the surface of highly oxidized carbon. The synthesis of phosphorilated carbon was considered, and the proton transfer reactions catalyzed by them in recent studies were analyzed. The development of an amorphous carbon acid catalyst comprising polycyclic carbonaceous （graphene） sheets with-SO3H,-COOH and phenolic type OH-groups was carried out. These new catalysts were synthesized by partial pyrolysis and subsequent sulfonation of carbohydrates, polymers, and other organic compounds. Their high catalytic activities in proton transfere reactions including the processing of bio-based raw materials was demonsrated.

关 键 词：固体酸催化剂 质子转移反应 碳材料 活性炭 热解 从头计算方法 羧酸基团 碳水化合物 

分 类 号：O643.32[理学—物理化学]