西佛碱型大环多胺过渡金属配合物的合成与表征  

Synthesis and Characterization of Transition Metal Complexes of Schiff Base Macrocyclic Polyamine

作　　者：王娟[1] 季振平 萧文锦[2] 

机构地区：[1]湖北大学化学与材料科学学院,武汉430062 [2]武汉大学化学与环境科学学院

出　　处：《应用化学》2001年第3期254-256,共3页Chinese Journal of Applied Chemistry

摘　　要：The synthesis of a Schiff base macrocyclic polyamine ligand and its five 1∶1 complexes with transition metals are reported. All compounds were characterized by elemental analysis, IR, UV Vis, 1H NMR, 13 C NMR, MS and molar conductance measurements. The results showed that [CuL](ClO 4) 2 is a square planar complex. The others are octahedral complexes.The synthesis of a Schiff base macrocyclic polyamine ligand and its five 1∶1 complexes with transition metals are reported. All compounds were characterized by elemental analysis, IR, UV Vis, 1H NMR, 13 C NMR, MS and molar conductance measurements. The results showed that [CuL](ClO 4) 2 is a square planar complex. The others are octahedral complexes.

关 键 词：西佛碱型大环多胺 过渡金属配合物 表征 

分 类 号：O641.4[理学—物理化学]