反应型阻燃剂中间体DOPO合成研究  

Synthesis and investigation of flame retardant DOPO

作　　者：张雪[1] 马会娟 李永刚 陈祖兴[1] 

机构地区：[1]湖北大学化学化工学院,湖北武汉430062 [2]湖北兴发化工集团公司,湖北宜昌443000

出　　处：《湖北大学学报（自然科学版）》2014年第4期351-353,共3页Journal of Hubei University：Natural Science

摘　　要：以三氯化磷、邻苯基苯酚为主要原料,氯化锌为催化剂,合成阻燃剂9,10-二氢-9-氧杂-10-膦杂菲-10-氧化物(DOPO),分析反应过程中产生的黄色副产物并确定其结构,通过优化合成工艺,有效地抑制黄色副产物的生成,DOPO为白色固体且纯度达99.5%以上,满足应用要求.A flame retardant 9,10-dihydro-9-oxa-10-phospha-phenanthrene-10-oxide （DOPO） was synthesized by phosphorus trichloride, o-phenylphenol as starting materials and zinc chloride as catalyst. The yellow by-products were analyzed and the structures were determined, their formation were effectively inhibited by optimizing the synthesis process. The purity of DOPO was above 99.5%, and it would meet the requirements and applications.

关 键 词：阻燃剂DOPO合成 副产物 

分 类 号：TB35[一般工业技术—材料科学与工程]