有机溶剂热生长晶体及其应用  

SOLVO-THERMAL SYNTHESIS OF METAL CHALCOGENIDES AND ITS EMPLOYMENT

作　　者：陈震[1] 郑曦[2] 陈日耀[2] 程蔚[2] 张义康[3] 

机构地区：[1]福建师范大学实验中心,福州市350007 [2]福建师范大学 [3]山东临沂教育学院

出　　处：《材料研究学报》2001年第2期151-158,共8页Chinese Journal of Materials Research

基　　金：福建省自然科学基金资助项目A9910009

摘　　要：介绍了有机溶剂热生长技术在金属碲、硒多聚物合成中的应用，并讨论了这类化合物的结构特征，及其在制备纳米级半导体薄膜。Solvo-thermal syntheses of metal chalcogenides have been overviewed. All three elements of S, Se and Te, have a tendency to catenate. This results not only in rings or chains of their several elemental forms, but also in the polychalcogenide Qn2-(Q=S, Se, Te, n=2-6) ions that can exist in solutions or in the solid-state in various sizes. Organic solvent is easy to reaction with precursor of transition metal to produce a complex canon in the solvo-thermal synthesis of metal chalcogenides. The technique can be employed in preparing a semiconductor film and using to prepare the catalyze carrier materials and relevant to many inportant processes, such as hydrodesulfurization of crude oil, hydrogenation of unsaturated and aromatic hydrocarbons, biosynthasis of metalloproteins, and even the hydrothermal conversion of metals to their binary chalcogenide minerals in nature.

关 键 词：有机溶剂热生长技术 无机多聚物 金属硫族化合物 晶体结构 半导体性质 晶体生长 催化性能 

分 类 号：O635[理学—高分子化学] O782[理学—化学]