水中芥子气水解产物硫二甘醇的分析  

Analysis of Hydrolysis Product of Mustard Gas Thiodiglycol in Water

作　　者：胡绪英[1] 娄艳红[1] 周永新[1] 

机构地区：[1]军事医学科学院毒物药物研究所,北京100850

出　　处：《分析测试学报》2001年第3期81-83,共3页Journal of Instrumental Analysis

摘　　要：建立了水中芥子气水解产物硫二甘醇HLB -H103固相萃取法 ,应用GC、GC -MS分析鉴定。该法操作简便、灵敏度高。方法回收率可达74 % ,检出限为0.A method for the determination of a hydrolysis product of mustard gas, thiodiglycol, in water was established. Thiodiglycol was collected on HLB-H103 column by solid phase extraction and eluted by 1%(φ) glacial acetic acid solution in methanol, then derivatized with BSTEA-TMCS(95∶5 by volume). The trimethylsilyl derivative was determined by GC and GC-MS. The method is convenient and sensitive. The extraction recovery of 74% and detection limit of 0.002 mg/L were found.

关 键 词：芥子气 硫二甘醇 固相萃取 气相色谱 气相色谱-质谱法 分析 水 毒剂 水解产物 

分 类 号：R991[医药卫生—毒理学] R996[医药卫生—药学]