Ag(I)与乙酰丙酮、乙酰乙酸乙酯、丙二腈及中性膦配合物的电化学合成  

Electrochemical Synthesis of Silver(I) Complexes with Acetylacetones, Ethylacetoacetate, Malononitrile and Ethylenebis(diphenylphosphine)

作　　者：汤德祥[1] 顾建胜[2] 刘卫华[2] 王璐[2] 

机构地区：[1]连云港师范高等专科学校化学系,江苏连云港222006 [2]苏州大学理学院化学化工系,江苏苏州215006

出　　处：《淮海工学院学报（自然科学版）》2001年第3期39-41,共3页Journal of Huaihai Institute of Technology:Natural Sciences Edition

摘　　要：用牺牲金属阳极的电化学方法合成了三种新的一价银配合物 Ag (I) (dppe) (CH(CN) 2 ) ,Ag(I) (dppe) (CH3COCHCOOEt)及 Ag(I) (dppe) (CH3COCHCOCH3) ,对配合物进行了元素分析、红外光谱测试及表征 ,并研究了反应的机理。The complexes of silver(I) with ethylenebis(diphenylphosphine) and acetylacetone, ethylacetoacetate, malononitrile were prepared by an electrochemical method in nonaqueous solutions. The products were characterized by elemental analysis, IR measurements as Ag(I)(dppe)(CH(CN) 2), Ag(I)(dppe) ( CH 3COCHCOOEt) and Ag(I) (dppe) (CH 3COCHCOCH 3) respectively. The electrochemical reactions were also studied.

关 键 词：银配合物 电化学合成 非水溶剂 乙酰丙酮 乙酰乙酸乙酯 丙二腈 

分 类 号：O614.122[理学—无机化学]