南部松小蠹集合信息素(±)-Frontalin的合成  

Synthesis of (±)-Frontalin, an Aggregation Pheromone of Bark Beetle

作　　者：高竹林[1] 殷彩霞[1] 李全[1] 刘复初[1] 朱洪友[1] 

机构地区：[1]云南大学化学系,昆明650091

出　　处：《应用化学》2001年第7期589-591,共3页Chinese Journal of Applied Chemistry

基　　金：云南省应用基础研究基金资助课题 (98C0 17M)

摘　　要：(±)-Frontalin (1,5-dimethyl-6,8-dioxabicycl octane), an aggregation pheromone of bark beetle, was prepared from cyclohexanone via a key intermediate 6-hepten-2-one prepared by catalytic decarbonylation of 7-oxo-octanoic acid with acetic anhydride using palladium(Ⅱ) complex as catalyst. The structures of all the compounds were confirmed by IR, MS, 1H NMR and 13C NMR.(±)-Frontalin (1,5-dimethyl-6,8-dioxabicycl octane), an aggregation pheromone of bark beetle, was prepared from cyclohexanone via a key intermediate 6-hepten-2-one prepared by catalytic decarbonylation of 7-oxo-octanoic acid with acetic anhydride using palladium(Ⅱ) complex as catalyst. The structures of all the compounds were confirmed by IR, MS, 1H NMR and 13C NMR.

关 键 词：南部松小蠹 集合信息素 弗罗塔林 合成 松林害虫 

分 类 号：S763.38[农业科学—森林保护学] Q965[农业科学—林学]