一类新型水溶性膦配体及其钠盐的合成  

Synthesis of New Type of Water-soluble Phosphine Ligands and their Disodium Salts

作　　者：马学兵[1] 陈文山[2] 傅相锴[2] 隋岩[2] 

机构地区：[1]四川大学化学学院,四川成都610064 [2]西南师范大学应用化学研究所,重庆北碚400715

出　　处：《分子催化》2001年第6期441-443,共3页Journal of Molecular Catalysis(China)

基　　金：重庆市科委资助课题 .

摘　　要：在温和的反应条件下 ,以季　盐 [Ph2 P(CH2 OH) 2 ]+ Cl-与含醚键和有机膦酸根的胺 H2 O3PCH2 CH2 N CH2 -CH2 (OCH2 CH2 ) n NH2 (n=1,2 ,3)的曼尼希反应 ,高产率合成了含 Ph2 PCH2 N=配位基团的水溶性膦配体 ,用NMR、 MS、 IR、The highly water\|soluble phosphine ligands, H\-2O\-3PCH\-2CH\-2N(CH\-2CH\-2O) n CH\-2CH\-2N(CH\-2PPh\-2)\-2 ( n =1,2,3), and their disodium salts were prepared with good yields by a new route using bis(hydroxymethyl)diphenylphosphonium chloride and N\|substituted 2\|aminoethylphosphonic acid, \{H\-2O\-3PCH\-2CH\-2N\|\}(CH\-2CH\-2O) n CH\-2CH\-2NH\-2 under mild conditions. The compounds 3a^3c were also characterized by IR, NMR and XPS.

关 键 词：合成 水溶性膦配体 有机金属配合物 催化剂 钠盐 结构表征 

分 类 号：O627.51[理学—有机化学] O643.36[理学—化学]