四种1-乙氧基-1-烷硫基丙烷类化合物的合成  

Synthesis of four 1-ethoxy-1-alkythiopropane compounds

作　　者：杨迎庆[1] 郑福平[1] 孙宝国[1] 刘玉平[1] 

机构地区：[1]北京工商大学化工学院,北京100037

出　　处：《化学试剂》2002年第1期5-7,48,共4页Chemical Reagents

基　　金：国家自然科学基金资助项目 (2 9872 0 0 4)

摘　　要：丙醛二乙缩醛分别与丁硫醇、仲丁硫醇、戊硫醇和糠硫醇在四氯化碳中 ,常温搅拌 2 0 min,减压下蒸出溶剂 (丙醛二乙缩醛与戊硫醇反应 ,常压蒸出溶剂 ) ,再减压蒸馏收集产物 ,可分别得到 1 -乙氧基 -1 -丁硫基丙烷、1 -乙氧基 -1 -仲丁硫基丙烷、1 -乙氧基 -1 -戊硫基丙烷和 1 -乙氧基 -1 -糠硫基丙烷 ,产率分别为 40 %、2 3 %、3 7%、60 %。此方法收集的产品中不易含有缩硫醛。经红外光谱、色 -质联机、核磁共振谱检测及硫元素含量分析 。1-Ethoxyl 1 butylthiopropane,1 ethoxyl 1 sec butylthiopropane,1 ethoxyl 1 amylthiopropane and 1 ethoxyl 1 furfurylthiopropane were synthesized by the reaction of propanal diethyl acetal with butyl mercaptan,sec butyl mercaptan,amyl mercaptan and furfuryl mercaptan,respectively,in carbon tetrachloride at room temperature for 20 min.The solvent was distilled at reduced pressure except for the synthesis of 1 ethoxy 1 amylthiopropane,where the solvent was distilled at normal pressure.The yields were 40%,23%,37% and 60%,respectively.Mercaptal were not detected in the products except in 1 ethoxyl 1 amylthiopropane.Structures of the four compounds were identified by IR,GC MS, 1HNMR and the analysis of sulfur content.

关 键 词：1-乙氧基-1-烷硫基丙烷 丙醛二乙缩醛 硫醇 合成 

分 类 号：O623.8[理学—有机化学]