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机构地区:[1]中国科学院福建物质结构研究所,福州350002
出 处:《物理学报》1991年第12期1960-1965,共6页Acta Physica Sinica
摘 要:本文介绍溶液降温法生长的大块邻苯二甲酸氢铷(RAP)单晶中关键有机基团的取向和性质对晶体生长习性的影响,并阐述结构中分子松散堆积与缺陷形成之间的关系。Large perfect crystals have been grown by using (001) seed plates from aqueous solution. It is shown that the great difference in the growth rates along positive and negative a-axis directions and the defect formation are closely related to the orientation of the key groups of carboxyl radicals(I) and the open structure (mainly the structural channels A and B), respectively. A proposal for improving the quality of crystals by changing the orientation of the polar axis a is given.
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