稀土金属(Nd)配合物的合成、表征及其性能研究  

Study on Synthesis of Complex Nd(C_8H_5O_4)_3(C_8H_6O_4)_10 and Its Optical and Electrochemical Properties

作　　者：徐娟[1] 蔡李鹏[1] 田瑶[1] 曾敏[1] 范玉桥 王娟[1] 

机构地区：[1]有机化工新材料湖北省协同创新中心湖北大学化学化工学院,湖北武汉430062

出　　处：《广州化工》2014年第13期59-60,63,共3页GuangZhou Chemical Industry

基　　金：湖北省自然科学基金资助项目(2012FFB00205);全国大学生创新训练项目(201210512054)

摘　　要：水热法合成了以对苯二甲酸和柠檬酸为配体的钕的配合物。通过红外、紫外、荧光、循环伏安法、热重分析对其进行了表征。结果表明，配合物在372 nm处具有较强的荧光发射峰，在-0.3～0.4 V的电势范围内研究配合物的电化学性质，研究结果表明，配合物在此电势范围内具有电化学活性。The research of a novel neodymium （Ⅲ） complex synthesized with terephthalic acid and citric acid as ligands by hydrothermal method was introduced.According to the infrared , ultraviolet , fluorescence and cyclic voltammetry, thermogravimetric analysis on the characterization , the results indicated that the complex had strong fluorescence emission peak at 372.0 nm.In the potential range of -0.3 ～0.4 V, electrochemical properties of the complex were researched , and it showed obvious electrochemical activity within the scope of this potential.

关 键 词：对苯二甲酸 钕 配合物 电化学 

分 类 号：O614.3[理学—无机化学]