3,5-二硝氨基-1,2,4-三唑肼盐的合成及性能（英文）  

A Novel Energetic Material Hydrazinium 3,5-Dinitroamino-1,2,4-triazole:Synthesis and Properties

作　　者：周诚[1] 王伯周[1] 霍欢[1] 周群[1] 杨威[1] 叶志虎[1] 

机构地区：[1]西安近代化学研究所,陕西西安710065

出　　处：《含能材料》2014年第4期576-578,共3页Chinese Journal of Energetic Materials

基　　金：Foundation Research Project of N ational Defence(B0920110051)

摘　　要：以硝基胍和甲醛为原料,经缩合反应、硝化反应和肼解反应得到总收率为63.69％的3,5-二硝氨基-1,2,4-三唑肼盐（HDNAT）,并对其进行了表征了结构.测试了HDNAT的部分物化、爆轰性能.结果为：密度1.89 g·cm^-3,熔点194 ～196℃摩擦感度92％,撞击感度1 00％,H50 26.8cm,爆速9000 m·s^-1（ρ=1.80 g·cm^-3）.采用VLM method计算其爆压为36.0 GPa.Abstract： A novel energetic material, hydrazinium 3,5-dinitroamino-1,2,4-triazole（HDNAT） was designed and synthesized for the first time via condensation, nitrification and hydrazinolysis reaction with a total yield of 63.69%. It＇s structure was characterized by 1 H NMR, 13C NMR, FT-IR and elemental analysis. In addition, some main properties of physico-chemistry and detonation for HDNAT were obtained by test or calculation. Re- suits show that its density is 1.89 g·cm^-3 , melting point 194-196℃, friction sensitivity 92%, impact sensitivity 100%, Hs0 26.8 cm, detonation velocity 9000 m·s^-1（p=l. 80 g·cm^-3 ） and detonation pressure 36.0 GPa calculated with VLM method.

关 键 词：有机化学 3 5-二硝氨基-1 2 4-三唑肼盐 合成 性能 

分 类 号：O621.3[理学—有机化学]