红外光声光谱技术应用于复合膜的原位剖面分析  

In Situ Depth Profiling of Complex Film by Fourier Transform Infrared Photoacoustic Spectroscopy

作　　者：陆宇振[1] 杜昌文[1] 周健民[1] 王娇[1] 

机构地区：[1]中国科学院南京土壤研究所土壤与农业可持续发展国家重点实验室,南京210008

出　　处：《分析化学》2014年第7期1028-1032,共5页Chinese Journal of Analytical Chemistry

基　　金：中国科学院知识创新重要方向项目(No.KZCX2-YW-QN411);国际植物营养研究所(IPNI)项目(No.Nanjing-11)资助~~

摘　　要：土壤颗粒在微观尺度上具有明显的异质性,表现为土壤有机质与矿物质的双层复合物结构。本研究以人工制备的复合膜样本为材料,采用红外光声光谱技术和独立成分分析对复合膜样本层进行原位剖面分析。复合膜样本由PE保鲜膜和办公胶带制备,红外光声光谱仪动静速率分别为0.16,0.32和0.64 cm/s。结果表明,通过改变光谱仪动静速率可以原位获取复合膜样本不同深度的组成信息,并估测出PE膜的厚度为5.4~7.6μm,与实际厚度（7±1）μm相接近；同时利用独立成分分析可以直接从复合膜样品的红外光声光谱中,同时分离出PE保鲜膜和胶带的光声光谱特征。红外光声光谱技术可对复合膜进行剖面分析,为进一步研究异质性土壤样本,特别是有机矿质复合体样本提供了新的分析手段。Soil particles are very heterogeneous in microscopic scale, which is manifested the double-layer structure made of the soil organic matter and mineral matter. In this work, Fourier by transform infrared photoacoustic spectroscopy （ FTIR-PAS） combined with independent component analysis （ ICA） was utilized for in situ depth-profiling of the manmade complex film, in order to lay a foundation of in situ characterizing the heterogeneous soil organic-mineral complex. The complex film was composed of the PE preservative film and office adhesive tape. The moving velocity of infrared photoacoustic spectrometer was set to 0. 16 cm/s, 0. 32 cm/s and 0. 64 cm/s, respectively. Independent component analysis （ ICA ） was performed on the photoacoustic spectra of the heterogeneous complex film. Results showed that the depth-resolved information of the complex film could be derived by changing the moving velocity, and the estimated thickness of PE film was 5. 4-7. 6 μm, which was close to the actual thickness 7 ± 1 μm. Moverover, the spectral features of the polyethylene （ PE） preservative film and office adhesive tape were extracted from the photoacoustic spectra of the heterogeneous complex film by means of ICA. Depth profiling of complex film samples showed that FTIR-PAS could be used as a new analytical tool to study heterogeneous soils, especially soil organic-mineral complexes.

关 键 词：红外光声光谱 剖面分析 复合膜 独立成分分析 

分 类 号：O657.33[理学—分析化学] S153.1[理学—化学]