气相色谱/质谱联用测定纺织品中5种苯酚类化合物  

Determination of 5 phenol compounds in textiles by GC/MS

作　　者：顾娟红[1] 潘葵[1] 黄丽娟[1] 严敏[1] 

机构地区：[1]苏州出入境检验检疫局,江苏苏州215104

出　　处：《印染助剂》2014年第9期46-48,共3页Textile Auxiliaries

基　　金：江苏出入境检验检疫局科研项目(2013KJ27)

摘　　要：探讨了气相色谱／质谱（GC／MS）联用测定纺织品中4种含氯酚及邻苯基苯酚残留量的方法．样品经甲醇超声提取、浓缩后，用0．1mol／L的硼砂溶液溶解，再经乙酸酐乙酰化后用正己烷提取，GC／MS测定，外标法定量．在0．05～2．5mg／L，方法的线性关系良好，相关系数为0．9990~0．9995，加标回收率为89％～105％，相对标准偏差为1．46％～5．32％．该方法简便、快速、灵敏度高，完全可满足进出口纺织品中4种含氯酚及邻苯基苯酚残留量检测的要求．Method for simultaneous determination of content of 4 chlorophenols and o-phenylphenol in textiles by gas chromatography/mass spectrometry （GC/MS） was established. The sample was extracted with methanol in ultrasonic bath. The extract was concentrated and dissolved in 0.1 mol/L borax solution, then de- rivatized by acetic anhydride and extracted by hexane. The targets of compounds were analyzed by GC/MS with external standard method. The result indicated that the calibration curves showed good linear relation- ships between the peak area and concentration in the range of 0.05-2.5 mg/L. The correlation coefficients were in the range of 0.999 0N0.999 5, The average recoveries ranged 89%N105% with relative standard devia- tions of 1.46% N5.32%. The method was simple, rapid and sensitive, and was suitable for the determination of 4 chlorophenols and o-phenylphenol in the import and export of textiles.

关 键 词：纺织品 氯酚 邻苯基苯酚 气相色谱 质谱 

分 类 号：TQ207.4[化学工程—有机化工]