二叠氮基乙二肟合成及表征  

Synthesis and Characterization of Diazidoglyoxime

作　　者：王小军[1,2] 苏强[1,2] 张广源[1,2] 王霞 王俊峰[2] 

机构地区：[1]甘肃银光化学工业集团有限公司,甘肃白银730900 [2]北京理工大学材料科学与工程学院,北京100081

出　　处：《含能材料》2014年第6期741-743,共3页Chinese Journal of Energetic Materials

摘　　要：以40%乙二醛水溶液和盐酸羟胺为原料,通过取代、氯化、叠氮化反应制备了二叠氮基乙二肟(DAG),并以元素分析,红外光谱(IR),核磁(NMR)对产物结构进行表征。测定了二叠氮基乙二肟的性能,撞击感度H50为17.5 cm,摩擦感度为36%。研究了反应介质、温度对叠氮化得率的影响,确定了叠氮化最佳的反应条件为:溶剂为N,N-二甲基甲酰胺(DMF),反应温度0℃,叠氮化收率为81.3%。Diazidoglyoxime was synthesized using solution glyoxal（40% w/w in H2 O）and hydroxylammonium as starting materi-als through substitution,chloration and nitrine reaction. Its structure was characterized by IR,elemental analysis and NMR. Re-sults show that the impact sensitivity H50 is 17. 5 cm,and the friction sensitivity is 36%. Based on the study of effects of the nitrine reaction,the optimal reaction conditions were determined as following：reaction medium is dimethyl formamide,reaction temper-ature 0 ℃,and the yied of nitrine reaction 81 . 3%.

关 键 词：有机化学 含能材料 二叠氮基乙二肟 合成 

分 类 号：TQ563[化学工程—炸药化工]