一种新型硫杂杯[4]芳烃冠醚衍生物的合成与配合性能  

Synthesis and characterization of novel thiacalix[4] crowns derivatives

作　　者：赵夏[1] 杨发福[2] 

机构地区：[1]银川能源学院石油化工系,银川750105 [2]福建师范大学化学与材料学院,福州350007

出　　处：《华中师范大学学报（自然科学版）》2015年第1期83-86,共4页Journal of Central China Normal University：Natural Sciences

基　　金：国家自然科学基金项目(20402002);福建省自然科学基金项目(E0220002;2009J019);银川能源学院科学研究资助项目(2013-KY-Z-05)

摘　　要：在普通杯芳烃中引入硫、氮原子可以改善普通杯芳烃的配合性能.在弱酸的催化下,使用硫杂杯[4]芳烃四酰肼衍生物3与芳醛衍生物4反应,高产率地合成了新型的含酰胺和席夫碱单元的硫杂杯[4]芳烃冠醚衍生物5,所合成的新化合物的结构经1 H NMR、元素分析、ESI-MS等证实.同时探讨了新型硫杂杯[4]芳烃衍生物5与系列α-氨基酸的配合性能,结果表明所合成的硫杂杯芳烃冠醚对氨基酸分子表现出有效的配合能力和选择性.The performance of ordinary calixarene can be improved with introducing of sulfur,nitrogen atom.Treatment of thiacalix[4]arene hydrazides derivative 3with aryl aldehyde derivatives 4,the novel thiacalix[4]crowns derivatives 5containing amides and schiffbase units were synthesized in high yields with the weak acid catalyst.The new compounds were characterized by elemental analyses,ESI-MS,1 H NMR spectra.At the same time,we studied the coordination properties of novel thiacalix[4]arene derivatives 5and series of alpha amino acids.The results showed that the thiacalixarene crown have an effective coordination ability and selectivity on amino acids.

关 键 词：硫杂杯[4]芳烃 合成 冠醚 氨基酸 

分 类 号：O623[理学—有机化学]