Cr12MoV冷作模具钢渗硼层表面与界面分析  

Analysis of Surface-interface of Boronized Layer on Cr12MoV Cold-worked Die Steel

作　　者：孔德军[1,2] 谢春洋[1] 

机构地区：[1]常州大学机械工程学院,江苏常州213164 [2]常州大学江苏省材料表面科学与技术重点实验室,江苏常州213164

出　　处：《兵工学报》2015年第3期571-576,共6页Acta Armamentarii

基　　金：江苏省科技支撑计划(工业)项目(BE2014818);中国学位与研究生教育学会研究课题(C1-2013Y07-051)

摘　　要：采用热浸渗法对Cr12MoV冷作模具钢进行渗硼处理,通过扫描电镜、能量色谱和X射线衍射分析渗硼层表面-界面形貌、化学元素分布和物相组成,对结合界面进行线扫描和面扫描分析,讨论了热浸法渗硼机理,并对残余应力和残余奥氏体进行测试。测试结果表明:渗硼层表面存在着细小气孔,与不溶于硼化物的原子扩散相关;渗硼层表面形成的高硬Fe B按照(002)方向择优生长;渗硼层结合界面化学元素发生相互扩散,元素分布均匀;渗硼处理后表面残余应力由拉应力变为压应力,同时残余奥氏体转变为马氏体,改善了冷作模具的摩擦与磨损性能。The surface of Cr12MoV cold-worked die steel is boronized by the method of hot-dipping, and the surface and interface morphologies and the chemical and phase compositions are analyzed by SEM, EDS and XRD, respectively. The residual stress and retained austenite on the surface are analyzed, and the hot-dipped boronizing mechanism is discussed. The results show that the tiny pores exist on the sur- face of boronized layer, and are related to the elements which are not solubled in boride. FeB is formed in the diffusion layer that has a preferred orientation in crystal plane （002） , and the chemical reactions and mutual diffusion of elements occur in the layer. The surface residual stress is changed from tensile stress to compressive stress, and the retained austenite is transformed into martensite after boronizing, which improves the friction and wear properties of cold-worked die steel.

关 键 词：材料表面与界面 CR12MOV钢 渗硼处理 表面-界面 残余应力 残余奥氏体 

分 类 号：TN249[电子电信—物理电子学] TG115.5[金属学及工艺—物理冶金]